caa a22 4500 445328762 CHVBK 20180317142730.0 cr unu---uuuuu 170323e20110201xx s 000 0 eng 10.1007/s10953-010-9644-4 doi (NATIONALLICENCE)springer-10.1007/s10953-010-9644-4 Visak Zoran Centro Química Estrutural, Instituto Superior Técnico, Avenida Rovisco Pais 1, 1049-001, Lisboa, Portugal aut Phenomenological Interpretation of the Systems Exhibiting a Closed-Loop Liquid-Liquid Phase Diagram by Using a Simple g E-Model [Elektronische Daten] [Zoran Visak] A simple phenomenological g E-model based on the Flory-Huggins lattice theory was used to interpret critical behavior, excess properties and liquid-liquid equilibria of three aqueous systems that exhibit a closed-loop phase diagram: (2-butoxyethanol + water), (2,6-dimethylpyridine + water) and (tetrahydrofuran (THF) + water). The model showed flexibility in application and good performance in all the aforementioned properties. Since it describes with a very good accuracy both binodal (coexistence) curves and excess enthalpies, it was used to calculate the molar excess enthalpies of the phases in equilibrium which may be a useful task in practice. Springer Science+Business Media, LLC, 2011 Closed-loop phase diagram nationallicence Phenomenological g E-model nationallicence Florry-Huggins lattice theory nationallicence Excess properties nationallicence Binodal curve nationallicence Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/2(2011-02-01), 261-283 0095-9782 40:2<261 2011 40 10953 https://doi.org/10.1007/s10953-010-9644-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-010-9644-4 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Visak Zoran Centro Química Estrutural, Instituto Superior Técnico, Avenida Rovisco Pais 1, 1049-001, Lisboa, Portugal aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/2(2011-02-01), 261-283 0095-9782 40:2<261 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer