caa a22 4500 445385243 CHVBK 20180317143030.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s10924-011-0287-3 doi (NATIONALLICENCE)springer-10.1007/s10924-011-0287-3 Ionic Liquids as Environmentally Friendly Solvents in Macromolecules Chemistry and Technology, Part I [Elektronische Daten] [Shadpour Mallakpour, Zahra Rafiee] With the increasing emphasis on the environment and the need to find environmentally friendly solvent systems, ionic liquids (IL)s have been emerging as promising green solvents to replace conventional solvents in recent years. They possess unique properties such as nonvolatility, low toxicity, ease of handling, nonflammability and high ionic conductivity; thus they have received much attention as green media for various chemistry processes. This report provides an extensive overview of use of ILs in polymers chemistry and technology. Springer Science+Business Media, LLC, 2011 Ionic liquids nationallicence Green chemistry nationallicence Polymers synthesis and modifications nationallicence [AMIM][Cl] : 1-Allyl-3-methylimidazolium chloride nationallicence [B4P][Cl] : Tetrabutylphosphonium chloride nationallicence [BDMIM][PF6] : 1-Butyl-2,3-dimethylimidazolium hexafluorophosphate nationallicence [BIEMIM][PF6] : 1-(2-Bromoisobutyryloxyethyl)-3-methylimidazolium hexafluorophosphate nationallicence [BIM][BF4] : 1-Butylimidazolium tetrafluoroborate nationallicence [BIM][TSA] : 1-Butylimidazolium p-toluenesulfonate nationallicence [BIM][NO3] : 1-Butylimidazolium nitrate nationallicence [BMIM][BF4] : 1-Butyl-3-methylimidazolium tetrafluoroborate nationallicence [BMIM][Cl] : 1-Butyl-3-methylimidazolium chloride nationallicence [BMIM][AlCl4] : 1-Butyl-3-methylimidazolium tetrachloroaluminate nationallicence [BMIM][SnCl3] : 1-Butyl-3-methylimidazolium chlorostannate nationallicence [BMIM][H2PO4] : 1-Butyl-3-methylimidazolium dihydrogen phosphate nationallicence [BMIM][HSO4] : 1-Butyl-1-methylimidazolium hydrogen sulphate nationallicence [BMIM][MDEGSO4] : 1-Butyl-3-methylimidazolium diethylene glycol monomethyl ether sulfate nationallicence [BMIM][N(CN)2] : 1-Butyl-3-methylimidazolium dicyanamide nationallicence [BMIM][OctSO4] : 1-Butyl-3-methylimidazolium octyl sulfate nationallicence [BMIM][PF6] : 1-Butyl-3-methylimidazolium hexafluorophosphate nationallicence [BMIM][Tf2N] : 1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide nationallicence [BMMor1,4][BF4] : N-butyl-N-methyl morpholinium tetrafluoroborate nationallicence [BMPyrr][Tf2N] : N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide nationallicence [BPyr][Cl] : N-butylpyridinium chloride nationallicence [BPyr][AlCl4] : N-butylpyridiunium tetrachloroaluminate nationallicence [Bu4N][Br] : Tetrabutylammonium bromide nationallicence [OTf] : Trifluoromethanesulfonate nationallicence [C18MIM][Cl] : 1-Octadecyl-3-methylimidazolium chloride nationallicence [C n MIM][PF6] : 1-Alkyl-3-methylimidazolium hexafluorophosphate nationallicence [C n Pyr][Tf2N] : N-alkylpyridinium bis(trifluoromethanesulfonyl)amide nationallicence [DEME][Tf2N] : N,N-diethyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)amide nationallicence [C12MIM][BF4] : 1-Dodecyl-3-methylimidazolium tetrafluoroborate nationallicence [EDMIM][Tf2N] : 1-Ethyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)amide nationallicence [EIM][TFA] : 1-Ethylimidazolium trifluoroacetate nationallicence [EMIM] : 1-Ethyl-3-methylimidazolium nationallicence [EMIM][AlCl4] : 1-Ethyl-3-methylimidazolium tetrachloroaluminate nationallicence [EMIM][OTf] : 1-Ethyl-2,3-dimethylimidazolium trifluoromethanesulfonate nationallicence [EMIM][HexSO4] : 1-Ethyl-3-methylimidazolium hexyl sulfate nationallicence [EMIM][I] : 1-Ethyl-3-methylimidazolium iodide nationallicence [EMIM][Tf2N] : 1-Ethyl-3-methylimidazolium bis(trifluoromethanesul-fonyl)amide nationallicence [EMIM][TSA] : 1-Ethyl-3-methylimidazolium tosylate nationallicence [EMIM][EtSO4] : 1-Ethyl-3-methylimidazolium ethylsulfate nationallicence [EtNH3][NO3] : Ethylammonium nitrate nationallicence [HMIM][BF4] : 1-Hexyl-3-methylimidazolium tetrafluoroborate nationallicence [HPyr][Tf2N] : N-hexylpyridinium bis(trifluoromethanesulfonyl)amide nationallicence [IM][BF4] : Imidazolium tetrafluoroborate nationallicence [Me3S][Tf2N] : Trimethylsulfonium bis(trifluoromethanesulfonyl)amide nationallicence [MMIM]Me2PO4] : 1,3-Dimethylimidazolium dimethylphosphate nationallicence [OMIM][BF4] : 1-Octyl-3-methylimidazolium tetrafluoroborate nationallicence [OMIM][PF6] : 1-Octyl-3-methylimidazolium hexafluorophosphate nationallicence [PF6] : Hexafluorophosphate nationallicence [PMIM][PF6] : 1-Propyl-3-methylimidazolium hexafluorophosphate nationallicence [Tf2N] : Bis(trifluoromethanesulfonyl)amide nationallicence AFM : Atom force microscopy nationallicence AN : Acrylonitrile nationallicence ANI : Aniline nationallicence ATR-FTIR : Attenuated total reflection Fourier transform infrared spectroscopy nationallicence ATRP : Atom transfer radical polymerization nationallicence BA : Butyl acrylate nationallicence BLG-NCA : γ-Benzyl-l-glutamate-N-carboxyanhydride nationallicence BMA : n-butyl methacrylate nationallicence BPO : Benzoyl peroxide nationallicence CAL-B : Candida antarctica lipase B nationallicence ChMI : N-cyclohexylmaleimide nationallicence CTA : Chain transfer agent nationallicence DCM : Dichloromethane nationallicence DPHLi : Diphenylhexyl lithium nationallicence DSC : Differential scanning calorimetry nationallicence DSSC : Dye sensitised solar cells nationallicence EC : Ethylene carbonate nationallicence EOX : 3-Ethyl-3-hydroxymethyloxetane nationallicence EPN-Br : Ethyl-2-bromopropionate nationallicence EQCM : Electrochemical quartz-crystal microbalance nationallicence [Et4N][BF4] : Tetraethylammonium tetrafluoroborate nationallicence GMA : Glycidyl methacrylate nationallicence GTP : Group transfer polymerization nationallicence HBOB : Bis(oxalato)boric acid nationallicence HexT : 3-Hexylthiophene nationallicence HPMA : 2-Hydroxypropyl methacrylate nationallicence IA : Isophthalic acid nationallicence ILs : Ionic liquids nationallicence ITO : Indium tin oxide nationallicence k p : Rate constant of propagation nationallicence k t : Rate constant of termination nationallicence MA : Methyl acrylate nationallicence MALDI-TOF : Matrix-assisted laser desorption/ionization time-of-flight nationallicence MAN : Methacrylonitrile nationallicence MDOB : 1,2-Methylenedioxybenzene nationallicence MeT : 3-Methylthiophene nationallicence MMA : Methyl methacrylate nationallicence Mn : Number-average molecular weight nationallicence Mr : Relative molecular mass nationallicence MnMA : Menthyl methacrylate nationallicence MITO : Modified indium tin oxide nationallicence MW : Molecular weight nationallicence MWD : Molecular weight distribution nationallicence NBMI : N-butylmaleimide nationallicence NMP : Nitroxide-mediated polymerization nationallicence NPhMI : N-phenylmaleimide nationallicence OcT : 3-Octylthiophene nationallicence PAN : Poly(acrylonitrile) nationallicence PANI : Polyaniline nationallicence PBMA : Poly(n-butylmethacrylate) nationallicence PClT : Poly(3-chlorothiophene) nationallicence PD : Polydispersity nationallicence PDI : Polydispersity index nationallicence PEDOT : Poly(3,4-ethylenedioxythiophene) nationallicence PEO : Poly(ethylene oxide) nationallicence PET : Poly(ethylene terephthalate) nationallicence PFPT : Poly(3-(4-fluorophenyl) thiophene) nationallicence PLA : Poly(lactide) nationallicence PLP : Pulsed laser polymerization nationallicence PMDETA : Pentamethyldiethylenetriamine nationallicence P(MEH-PPV) : Poly(2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylene vinylene) nationallicence PPP : Poly(p-phenylene) nationallicence PSt : Polystyrene nationallicence P(VdF-HFP) : Poly(vinylidene fluoride-co-hexafluoropropylene) nationallicence Py : Pyrrole nationallicence PTMC : Poly(trimethylene carbonate) nationallicence r p : Rate of propagation nationallicence r t : Rate of termination nationallicence RAFT : Reversible addition-fragmentation chain transfer nationallicence ROGP : Ring-opening graft polymerization nationallicence ROMP : Ring-opening metathesis polymerization nationallicence RTILs : Room-temperature ILs nationallicence SA : Succinic acid nationallicence SAXS : Small-angle X-ray scattering nationallicence SEM : Scanning electron microscopy nationallicence St : Styrene nationallicence T : Thiophene nationallicence Tg : Glass-transition temperature nationallicence THF : Tetrahydrofuran nationallicence TGA : Thermogravimetric analysis nationallicence TEMPO : 2,2,6,6-Tetramethyl-1-piperidinyloxy nationallicence TMPPAH : 2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane nationallicence TT : Terthiophene nationallicence VAc : Vinyl acetate nationallicence [VBBIM][BF4] : 1-(4-vinylbenzyl)-3-butyl imidazolium tetrafluoroborate nationallicence ε-CL : ε-Caprolactone nationallicence WAXD : Wide angle X-ray scattering nationallicence Mallakpour Shadpour Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, 84156-83111, Isfahan, Iran aut Rafiee Zahra Department of Chemistry, Yasouj University, 75914-35, Yasouj, Iran aut Journal of Polymers and the Environment Springer US; http://www.springer-ny.com 19/2(2011-06-01), 447-484 1566-2543 19:2<447 2011 19 10924 https://doi.org/10.1007/s10924-011-0287-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10924-011-0287-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mallakpour Shadpour Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, 84156-83111, Isfahan, Iran aut NATIONALLICENCE 700 1- Rafiee Zahra Department of Chemistry, Yasouj University, 75914-35, Yasouj, Iran aut NATIONALLICENCE 773 0- Journal of Polymers and the Environment Springer US; http://www.springer-ny.com 19/2(2011-06-01), 447-484 1566-2543 19:2<447 2011 19 10924 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 445385243 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer