caa a22 4500 445387912 CHVBK 20180317143037.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s11144-011-0285-4 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0285-4 Zhdanov Vladimir Competence Centre for Catalysis, Chalmers University of Technology, 41296, Gothenburg, Sweden aut A kinetic model of standard selective catalytic reduction of NO by NH3 on single sites [Elektronische Daten] [Vladimir Zhdanov] Reduction of NO by NH3 in the presence of O2 may occur on single Fe or Cu atoms or dimers incorporated into the inner walls of a zeolite. Although this process is of considerable intrinsic interest as an example of complex reactions running on single sites and is also important from the perspective of environmental chemistry, its mechanism is still open for debate. One of the likely schemes of the process implies the formation of N2 and H2O via the reaction of gas-phase NO and adsorbed NH3. The author presents a detailed analysis of the steady-state kinetics corresponding to this scheme. The model employed includes eleven elementary steps. The results obtained allow one to interpret the apparent reaction orders observed experimentally. Akadémiai Kiadó, Budapest, Hungary, 2011 Kinetics nationallicence Surface chemical reactions nationallicence Single catalytic sites nationallicence Reaction orders nationallicence NO, NH3, O2, N2, H2O nationallicence Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 11-18 1878-5190 103:1<11 2011 103 11144 https://doi.org/10.1007/s11144-011-0285-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0285-4 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Zhdanov Vladimir Competence Centre for Catalysis, Chalmers University of Technology, 41296, Gothenburg, Sweden aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 11-18 1878-5190 103:1<11 2011 103 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 445387912 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer