caa a22 4500 445387920 CHVBK 20180317143037.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s11144-011-0289-0 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0289-0 Substituted N -hydroxyphthalimides as oxidation catalysts [Elektronische Daten] [K. Novikova, M. Kompanets, O. Kushch, S. Kobzev, M. Khliestov, I. Opeida] A series of substituted N-hydroxyphthalimides (NHPI) with electron-withdrawing groups (4-C(O)OH, C=O) and an electron-donating group (4-C(CH3)3) were investigated as catalysts for cumene oxidation. The initial reaction rates, measured by the oxygen uptake, conversion of substrate and yield of oxidation products are discussed. The catalytic activity of oxidation rate enhancement of NHPI derivatives in acetonitrile follows the order 4-tert-BuNHPI>NHPI>4-carb-NHPI>NDHPI>NAPI. NMPT, trityl-NPI and NHPLI are inactive. Akadémiai Kiadó, Budapest, Hungary, 2011 N -hydroxyphthalimide nationallicence Homogenous catalysis nationallicence Aerobic oxidation nationallicence Cumene nationallicence BDE nationallicence Novikova K. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut Kompanets M. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut Kushch O. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut Kobzev S. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut Khliestov M. Department of chemistry, Donetsk national university, Donetsk, Ukraine aut Opeida I. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 31-40 1878-5190 103:1<31 2011 103 11144 https://doi.org/10.1007/s11144-011-0289-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0289-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Novikova K. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut NATIONALLICENCE 700 1- Kompanets M. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut NATIONALLICENCE 700 1- Kushch O. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut NATIONALLICENCE 700 1- Kobzev S. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut NATIONALLICENCE 700 1- Khliestov M. Department of chemistry, Donetsk national university, Donetsk, Ukraine aut NATIONALLICENCE 700 1- Opeida I. L.M. Litvinenko Institute of physico-organic and coal chemistry of NASU, R. Luxemburg Street 70, 83114, Donetsk, Ukraine aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 31-40 1878-5190 103:1<31 2011 103 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer