caa a22 4500 445387939 CHVBK 20180317143037.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s11144-011-0299-y doi (NATIONALLICENCE)springer-10.1007/s11144-011-0299-y Modelling of an annular photocatalytic reactor [Elektronische Daten] [M. Marečić, F. Jović, V. Kosar, V. Tomašić] This work deals with the photocatalytic oxidation of toluene at room temperature and atmospheric pressure in the gas phase. The differential equations of the reactor model are solved numerically with simultaneous estimation of the model parameters. Estimation of the kinetic data is performed using a modified differential method of data analysis and a Nelder-Mead method of nonlinear optimization for parameter estimation. The reaction is performed in an annular photoreactor using UVA black light blue fluorescent lamp. The experiments are carried out at different total flow rates of the reaction feed (20-160cm3min−1), two different inlet concentrations of toluene (2.67 and 5.24gm−3) and at constant relative humidity (25%). A good agreement between the experimental data and theoretical predictions is obtained, supporting the applicability of the proposed models to describe the investigated process performed in laboratory annular photoreactor. Akadémiai Kiadó, Budapest, Hungary, 2011 Annular reactor nationallicence Mathematical models nationallicence Photocatalytic oxidation nationallicence Toluene nationallicence Marečić M. Department of Food Technology and Biotechnology, University of Zagreb, Zagreb, Croatia aut Jović F. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut Kosar V. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut Tomašić V. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 19-29 1878-5190 103:1<19 2011 103 11144 https://doi.org/10.1007/s11144-011-0299-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0299-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Marečić M. Department of Food Technology and Biotechnology, University of Zagreb, Zagreb, Croatia aut NATIONALLICENCE 700 1- Jović F. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut NATIONALLICENCE 700 1- Kosar V. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut NATIONALLICENCE 700 1- Tomašić V. Department of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/1(2011-06-01), 19-29 1878-5190 103:1<19 2011 103 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer