caa a22 4500 445388099 CHVBK 20180317143038.0 cr unu---uuuuu 170323e20110801xx s 000 0 eng 10.1007/s11144-011-0310-7 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0310-7 Alkylation of anisole with 1-hexene and 1-hexanol over zeolite H-beta [Elektronische Daten] [P. Surse, S. Wagholikar, S. Mayadevi, S. Sivasanker] An examination of the kinetics of the alkylation of anisole with 1-hexene and 1-hexanol to produce alkylates over zeolite H-beta is presented. Anisole alkylation is found to occur by a set of parallel reactions when hexene is used as the alkylating agent. When hexyl alcohol is the alkylating agent, the reaction follows a multi-step parallel-series mechanism to form monoalkylates and dihexylether. With 1-hexene, a group of isomeric alkylates, viz., ortho-2-hexyl anisole (2-OHA), ortho-3-hexyl anisole (3-OHA), para-2-hexyl anisole (2-PHA), and para-3-hexyl anisole (3-PHA) was obtained. With hexanol, the olefin (hexene) and dihexyl ether were obtained additionally. The influence of process parameters like temperature, catalyst quantity, and alkylating agent on reaction behavior is reported. Akadémiai Kiadó, Budapest, Hungary, 2011 Alkylation nationallicence Anisole nationallicence Hexene nationallicence Hexyl alcohol nationallicence H-beta nationallicence Surse P. National Chemical Laboratory, 411008, Pune, India aut Wagholikar S. National Chemical Laboratory, 411008, Pune, India aut Mayadevi S. National Chemical Laboratory, 411008, Pune, India aut Sivasanker S. National Chemical Laboratory, 411008, Pune, India aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/2(2011-08-01), 481-491 1878-5190 103:2<481 2011 103 11144 https://doi.org/10.1007/s11144-011-0310-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0310-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Surse P. National Chemical Laboratory, 411008, Pune, India aut NATIONALLICENCE 700 1- Wagholikar S. National Chemical Laboratory, 411008, Pune, India aut NATIONALLICENCE 700 1- Mayadevi S. National Chemical Laboratory, 411008, Pune, India aut NATIONALLICENCE 700 1- Sivasanker S. National Chemical Laboratory, 411008, Pune, India aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 103/2(2011-08-01), 481-491 1878-5190 103:2<481 2011 103 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer