caa a22 4500 445388226 CHVBK 20180317143038.0 cr unu---uuuuu 170323e20111001xx s 000 0 eng 10.1007/s11144-011-0335-y doi (NATIONALLICENCE)springer-10.1007/s11144-011-0335-y Ethanol and dimethyl ether steam reforming on Rh/Al2O3 catalysts for high-temperature fuel-cell feeds [Elektronische Daten] [E. Gucciardi, V. Chiodo, S. Freni, S. Cavallaro, A. Galvagno, J. Bart] Catalytic reactions of the steam reforming (SR) of dimethyl ether (DME) and (bio)ethanol to hydrogen-rich gas were compared in a fixed-bed continuous-flow reactor at temperatures of 550-650°C under atmospheric pressure over Rh/Al2O3 catalysts in terms of product distribution. Rh/Al2O3 catalysts are able to catalyze the high-temperature SR of both EtOH and DME, but in the latter case, higher H2 yields are obtained and the catalyst is less prone to coking. The aim of this work is to optimise the hydrogen production. Differences in reaction pathways over DME/H2O and EtOH/H2O are indicated. Akadémiai Kiadó, Budapest, Hungary, 2011 Steam reforming nationallicence Hydrogen nationallicence DME nationallicence Ethanol nationallicence Dimethyl ether nationallicence Gucciardi E. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut Chiodo V. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut Freni S. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut Cavallaro S. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut Galvagno A. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut Bart J. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 75-87 1878-5190 104:1<75 2011 104 11144 https://doi.org/10.1007/s11144-011-0335-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0335-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gucciardi E. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut NATIONALLICENCE 700 1- Chiodo V. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut NATIONALLICENCE 700 1- Freni S. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut NATIONALLICENCE 700 1- Cavallaro S. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut NATIONALLICENCE 700 1- Galvagno A. Istituto CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126, Messina, ME, Italy aut NATIONALLICENCE 700 1- Bart J. Department of Industrial Chemistry and Materials Engineering, University of Messina, V.le F. Stagno d'Alcontres 31, Sant'Agata di, 98166, Messina, ME, Italy aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 75-87 1878-5190 104:1<75 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer