caa a22 4500 445388269 CHVBK 20180317143038.0 cr unu---uuuuu 170323e20111001xx s 000 0 eng 10.1007/s11144-011-0328-x doi (NATIONALLICENCE)springer-10.1007/s11144-011-0328-x Oxidation of cyclohexane with tert -butylhydroperoxide and hydrogen peroxide catalyzed by nano-sized γ-alumina supported metallophthalocyanines [Elektronische Daten] [Amin Ebadi, Fatemeh Nikbakht] In this study, nano-γ-alumina-supported unsubstituted Fe-, Co- and Mn-phthalocyanines were prepared and characterized. Catalytic activities of the supported phthalocyanines for the oxidation of cyclohexane with tert-butylhydroperoxide (TBHP) and H2O2 as the oxidant in the liquid phase were considered. For the MPc/nano-γ-alumina catalysts, a dimethylformamide:dichloromethane (3:7) solvent mixture was employed. The products of the catalytic reaction are cyclohexanone and cyclohexanol. The conversion percent of cyclohexane depended on the oxidant and the catalyst. TBHP was found to be a better oxidant than H2O2 since minimal destruction of the catalyst and higher conversion of cyclohexane were observed when this oxidant was employed. Under these reaction conditions, the order of catalytic activities is as follows: CoPc/γ-alumina>FePc/γ-alumina>MnPc/γ-alumina. Over γ-alumina, the conversion was much lower than on supported catalysts. The highest conversion of cyclohexane (13.21%) was observed on 10% CoPc supported. Akadémiai Kiadó, Budapest, Hungary, 2011 Oxidation nationallicence γ-Alumina nationallicence Supported nationallicence Metallophthalocyanines nationallicence Cyclohexane nationallicence Ebadi Amin Department of Chemistry, Islamic Azad University, Kazerun Branch, Kazerun, Fars, Iran aut Nikbakht Fatemeh Department of Chemistry, Islamic Azad University, Kazerun Branch, Kazerun, Fars, Iran aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 37-47 1878-5190 104:1<37 2011 104 11144 https://doi.org/10.1007/s11144-011-0328-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0328-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ebadi Amin Department of Chemistry, Islamic Azad University, Kazerun Branch, Kazerun, Fars, Iran aut NATIONALLICENCE 700 1- Nikbakht Fatemeh Department of Chemistry, Islamic Azad University, Kazerun Branch, Kazerun, Fars, Iran aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 37-47 1878-5190 104:1<37 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer