caa a22 4500 445388331 CHVBK 20180317143038.0 cr unu---uuuuu 170323e20111001xx s 000 0 eng 10.1007/s11144-011-0339-7 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0339-7 One-pot synthesis of highly ordered Ru-containing mesoporous polymers/silica for benzaldehyde hydrogenation [Elektronische Daten] [Liying Song, Kaixiang Li, Xiaohong Li, Peng Wu] Ordered Ru-containing mesoporous polymers/silica (xRu-MPS) was for the first time successfully synthesized via a one-pot method. Characterization results demonstrated that the xRu-MPS samples had ordered meso-structure and Ru nanoparticles were highly dispersed on/inside the mesoporous polymer/silica. The xRu-MPS catalysts were proved to be efficient for the hydrogenation of benzaldehyde and its derivatives. When the Ru loading reached up to 4.8wt%, the conversion of benzaldehyde could arrive 96% with 97% selectivity to benzyl alcohol. The 4.8Ru-MPS catalyst can also catalyze the hydrogenation of a series of benzaldehyde derivatives with different substituents at the phenyl ring with high performance. The results are quite comparable with those obtained on mesopolymer supported Ru catalyst prepared by a traditional impregnation method. Akadémiai Kiadó, Budapest, Hungary, 2011 One-pot synthesis nationallicence Mesoporous polymers/silica composites nationallicence Ru nanoparticles nationallicence Hydrogenation nationallicence Benzaldehydes nationallicence Song Liying Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut Li Kaixiang Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut Li Xiaohong Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut Wu Peng Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 99-109 1878-5190 104:1<99 2011 104 11144 https://doi.org/10.1007/s11144-011-0339-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0339-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Song Liying Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut NATIONALLICENCE 700 1- Li Kaixiang Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut NATIONALLICENCE 700 1- Li Xiaohong Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut NATIONALLICENCE 700 1- Wu Peng Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, 200062, Shanghai, China aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/1(2011-10-01), 99-109 1878-5190 104:1<99 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer