caa a22 4500 445388471 CHVBK 20180317143039.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11144-011-0370-8 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0370-8 Analysis of reaction mechanisms and kinetics of preferential CO oxidation over Au/γ-Al2O3 [Elektronische Daten] [Tugba Davran-Candan, Mehtap Demir, Ramazan Yildirim] In this work, the mechanism and kinetics of the preferential CO oxidation over 0.5 wt. % Au/Al2O3 catalyst was investigated. For CO oxidation, the reaction was found to follow a two-step Eley-Rideal-type mechanism, in which the formation and decomposition of the reaction intermediate took place at the gold-support interface. For the PROX case, on the other hand, Langmuir-Hinshelwood-type mechanisms seem to be also significant. Akadémiai Kiadó, Budapest, Hungary, 2011 Preferential CO oxidation nationallicence Gold catalysts nationallicence Au/γ-Al2O3 nationallicence Reaction mechanism nationallicence Reaction kinetics nationallicence Davran-Candan Tugba Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut Demir Mehtap Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut Yildirim Ramazan Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 389-398 1878-5190 104:2<389 2011 104 11144 https://doi.org/10.1007/s11144-011-0370-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0370-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Davran-Candan Tugba Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut NATIONALLICENCE 700 1- Demir Mehtap Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut NATIONALLICENCE 700 1- Yildirim Ramazan Department of Chemical Engineering, Bogazici University, 34342, Istanbul, Turkey aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 389-398 1878-5190 104:2<389 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer