caa a22 4500 445388498 CHVBK 20180317143039.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11144-011-0369-1 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0369-1 Development of a kinetic model of the Fischer-Tropsch synthesis reaction with a cobalt-based catalyst [Elektronische Daten] [Seung-Ho Kwack, Myung-June Park, Jong Bae, Kyoung-Su Ha, Ki-Won Jun] A kinetic model of cobalt-based Fischer-Tropsch synthesis was developed through the detailed kinetic study of the reaction mechanism. Experimental evidence and previously reported theoretical analyses were used to suggest the mechanism and derive reaction rates for the formation of hydrocarbon products by applying the equilibrium constants of the adsorbents and the quasi steady state assumption to intermediate species on the surface of the catalyst. The comparison between experimental data and simulated results with kinetic parameters validated the effectiveness of the developed model. Further analysis showed that temperature and H2/CO ratio significantly influenced the entire distribution of hydrocarbon products. The effects of operating conditions were also predicted in accordance with previous work, thus demonstrating that the developed model can contribute to a better understanding of the kinetic mechanism of FT synthesis. Akadémiai Kiadó, Budapest, Hungary, 2011 Cobalt-based catalyst nationallicence Fischer-Tropsch synthesis nationallicence Kinetics nationallicence Parameter estimation nationallicence Mathematical modeling nationallicence Kwack Seung-Ho Department of Chemical Engineering, Ajou University, 443-749, Suwon, Korea aut Park Myung-June Department of Chemical Engineering, Ajou University, 443-749, Suwon, Korea aut Bae Jong School of Chemical Engineering, Sungkyunkwan University, 440-746, Suwon, Korea aut Ha Kyoung-Su Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), 305-600, Daejeon, Korea aut Jun Ki-Won Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), 305-600, Daejeon, Korea aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 483-502 1878-5190 104:2<483 2011 104 11144 https://doi.org/10.1007/s11144-011-0369-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0369-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kwack Seung-Ho Department of Chemical Engineering, Ajou University, 443-749, Suwon, Korea aut NATIONALLICENCE 700 1- Park Myung-June Department of Chemical Engineering, Ajou University, 443-749, Suwon, Korea aut NATIONALLICENCE 700 1- Bae Jong School of Chemical Engineering, Sungkyunkwan University, 440-746, Suwon, Korea aut NATIONALLICENCE 700 1- Ha Kyoung-Su Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), 305-600, Daejeon, Korea aut NATIONALLICENCE 700 1- Jun Ki-Won Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), 305-600, Daejeon, Korea aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 483-502 1878-5190 104:2<483 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer