caa a22 4500 445388633 CHVBK 20180317143039.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11144-011-0363-7 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0363-7 Thermodynamic analysis of the cluster size evolution in catalyst preparation by deposition-precipitation [Elektronische Daten] [Dmitry Murzin, Olga Simakova, Irina Simakova, Valentin Parmon] Several gold catalysts supported on various inorganic supports with different point zero charge (pzc) were prepared by deposition-precipitation with urea (DPU). A thermodynamic model accounting for cluster evolution was advanced. The key element in the model is the dependence of the interfacial energy on the relative approach to pzc during DP. Experimental data were compared with the model, showing a possibility to utilize the theoretical approach to predict the cluster size. Akadémiai Kiadó, Budapest, Hungary, 2011 Thermodynamics nationallicence Cluster size nationallicence Growth nationallicence Catalyst preparation nationallicence Deposition-precipitation nationallicence Murzin Dmitry Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo, Finland aut Simakova Olga Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo, Finland aut Simakova Irina Boreskov Institute of Catalysis, Novosibirsk, Russia aut Parmon Valentin Boreskov Institute of Catalysis, Novosibirsk, Russia aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 259-266 1878-5190 104:2<259 2011 104 11144 https://doi.org/10.1007/s11144-011-0363-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0363-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Murzin Dmitry Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo, Finland aut NATIONALLICENCE 700 1- Simakova Olga Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo, Finland aut NATIONALLICENCE 700 1- Simakova Irina Boreskov Institute of Catalysis, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Parmon Valentin Boreskov Institute of Catalysis, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 259-266 1878-5190 104:2<259 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer