caa a22 4500 445388641 CHVBK 20180317143039.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11144-011-0353-9 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0353-9 Zhdanov Vladimir Competence Centre for Catalysis, Chalmers University of Technology, S-41296, Göteborg, Sweden aut A kinetic model of standard selective catalytic reduction of NO by NH3 on two sites [Elektronische Daten] [Vladimir Zhdanov] Reduction of NO by NH3 in the presence of O2 may occur on single Fe or Cu atoms or dimers incorporated into the inner walls of zeolite. One of the likely schemes of this reaction implies the formation of N2 and H2O through the reaction of gas-phase NO and adsorbed NH3. The steady-state kinetics corresponding to this scheme was recently analyzed by the author assuming that the reaction runs on single metal atoms. In this work, the author presents a model including two metal atoms. Under the practically important conditions, the kinetics predicted by the one- and two-site models are demonstrated to be similar. In particular, both models allow one to interpret the apparent reaction orders observed experimentally. Akadémiai Kiadó, Budapest, Hungary, 2011 Kinetics nationallicence Surface chemical reactions nationallicence Catalytic sites nationallicence Reaction orders nationallicence NO, NH3,O2,N2,H2O nationallicence Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 267-272 1878-5190 104:2<267 2011 104 11144 https://doi.org/10.1007/s11144-011-0353-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0353-9 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Zhdanov Vladimir Competence Centre for Catalysis, Chalmers University of Technology, S-41296, Göteborg, Sweden aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 267-272 1878-5190 104:2<267 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 445387912 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer