caa a22 4500 44538865X CHVBK 20180317143039.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11144-011-0348-6 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0348-6 Hydrolysis of carboxylic acid esters catalyzed by a carbon-based solid acid [Elektronische Daten] [Zhenwu Fu, Hui Wan, Qun Cui, Jiahua Xie, Yongjian Tang, Guofeng Guan] A carbon-based solid acid catalyst is prepared by incomplete carbonization of sulfonated naphthalene and used for the hydrolysis of carboxylic acid esters. XRD, FT-IR, TGA and acid density test are employed to characterize the structure and performance of the catalysts. The results show that the catalysts prepared under different synthesis temperature and time are amorphous carbon composed of small aromatic carbon sheets with -SO3H groups. The catalytic activities of catalysts for methyl acetate hydrolysis are closely related with their acid densities. The appropriate synthesis temperature and time for the catalyst are 230°C and 12h and the acid density of catalyst under the optimized conditions can reach 4.49mmolg−1. The carbon-based solid acid shows higher catalytic activity than Amberlyst-15 resin as a popular hydrolysis catalyst for a series of carboxylic acid esters hydrolysis. The catalyst has good thermal stability, which can bear 250°C without decomposition. It also remains satisfactory catalytic activity for methyl acetate hydrolysis after six times recycling. Akadémiai Kiadó, Budapest, Hungary, 2011 Carbon-based solid acid nationallicence Hydrolysis nationallicence Carboxylic acid esters nationallicence Catalytic activity nationallicence Fu Zhenwu College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Wan Hui College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Cui Qun College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Xie Jiahua College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Tang Yongjian College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Guan Guofeng College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 313-321 1878-5190 104:2<313 2011 104 11144 https://doi.org/10.1007/s11144-011-0348-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0348-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Fu Zhenwu College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 700 1- Wan Hui College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 700 1- Cui Qun College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 700 1- Xie Jiahua College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 700 1- Tang Yongjian College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 700 1- Guan Guofeng College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, People's Republic of China aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 104/2(2011-12-01), 313-321 1878-5190 104:2<313 2011 104 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer