caa a22 4500 445388897 CHVBK 20180317143040.0 cr unu---uuuuu 170323e20110401xx s 000 0 eng 10.1007/s11144-010-0264-1 doi (NATIONALLICENCE)springer-10.1007/s11144-010-0264-1 Photocatalytic degradation of aniline with boron-doped cryptomelane type manganese oxide [Elektronische Daten] [Shuijiao Liao, Duanwei Zhu, Yue Li, Guanglong Liu, Linghua Liu] The effect of boron doping on the photocatalytic activity of manganese (Mn) oxide in aniline degradation was investigated. Mn oxide was synthesized by the reaction of MnCl2 with KMnO4 and boron-doped Mn oxide (occluded-B-Mn oxide or oc-B-Mn oxide) was prepared by the reaction of MnCl2 with KMnO4 in the presence of boric acid. The structural formulas of the Mn oxide and the oc-B-Mn oxide were K0.04MnO1.90(H2O)0.54 and K0.04B0.01MnO1.87(H2O)0.61, respectively. Their physicochemical properties were characterized by XRD, TEM, BET and UV-Vis absorption spectra. The photocatalytic activity was evaluated by aniline degradation in aqueous catalyst dispersions under UV light radiation. Discussion of the results showed that the higher photocatalytic activity of the oc-B-Mn oxide may be attributed to the synergetic effect of light absorption, the specific surface area and the suppression of recombination of electron-hole pair. Akadémiai Kiadó, Budapest, Hungary, 2010 Boron doping nationallicence UV light nationallicence Photocatalysis nationallicence Mn oxide nationallicence Aniline nationallicence Liao Shuijiao College of Basic Sciences of Huazhong Agricultural University, 430070, Wuhan, China aut Zhu Duanwei Key Laboratory of Subtropical Agriculture and Environment, Ministry of Agriculture, Huazhong Agricultural University, 430070, Wuhan, China aut Li Yue College of Basic Sciences of Huazhong Agricultural University, 430070, Wuhan, China aut Liu Guanglong Key Laboratory of Subtropical Agriculture and Environment, Ministry of Agriculture, Huazhong Agricultural University, 430070, Wuhan, China aut Liu Linghua China Institute of Water Resources and Hydropower Research, 10003, Beijing, China aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 303-311 1878-5190 102:2<303 2011 102 11144 https://doi.org/10.1007/s11144-010-0264-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-010-0264-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Liao Shuijiao College of Basic Sciences of Huazhong Agricultural University, 430070, Wuhan, China aut NATIONALLICENCE 700 1- Zhu Duanwei Key Laboratory of Subtropical Agriculture and Environment, Ministry of Agriculture, Huazhong Agricultural University, 430070, Wuhan, China aut NATIONALLICENCE 700 1- Li Yue College of Basic Sciences of Huazhong Agricultural University, 430070, Wuhan, China aut NATIONALLICENCE 700 1- Liu Guanglong Key Laboratory of Subtropical Agriculture and Environment, Ministry of Agriculture, Huazhong Agricultural University, 430070, Wuhan, China aut NATIONALLICENCE 700 1- Liu Linghua China Institute of Water Resources and Hydropower Research, 10003, Beijing, China aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 303-311 1878-5190 102:2<303 2011 102 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer