caa a22 4500 445388927 CHVBK 20180317143040.0 cr unu---uuuuu 170323e20110401xx s 000 0 eng 10.1007/s11144-010-0280-1 doi (NATIONALLICENCE)springer-10.1007/s11144-010-0280-1 Catalytic performance of polymer-supported ionic liquids in the cycloaddition of carbon dioxide to allyl glycidyl ether [Elektronische Daten] [Jeong-In Yu, Hye-Ji Choi, Manickam Selvaraj, Dae-Won Park] Ionic liquids immobilized onto structurally modified Merrifield peptide resin (MPR) were prepared through the reaction of imidazole with alkoxylated MPR. Elemental analysis and SEM images showed that the immobilized ionic liquid groups were well incorporated onto the support. The MPR-supported ionic liquids (MPR-IL) proved to be effective heterogeneous catalysts for the solvent-free synthesis of a cyclic carbonate from allyl glycidyl ether (AGE) and carbon dioxide. MPR-ILs with longer alkyl chain linkers and sterically less hindered counteranions had higher conversions of AGE. High temperature, high carbon dioxide pressure and the presence of zinc halide co-catalyst were favorable for AGE conversion. MPR-IL can be reused for the reaction through up to three consecutive runs without significant loss of its catalytic activity. Akadémiai Kiadó, Budapest, Hungary, 2011 Ionic liquid nationallicence Merrifield resin nationallicence Carbon dioxide nationallicence Allyl glycidyl ether nationallicence Cyclic carbonate nationallicence Yu Jeong-In Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut Choi Hye-Ji Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut Selvaraj Manickam Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut Park Dae-Won Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 353-365 1878-5190 102:2<353 2011 102 11144 https://doi.org/10.1007/s11144-010-0280-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-010-0280-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yu Jeong-In Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut NATIONALLICENCE 700 1- Choi Hye-Ji Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut NATIONALLICENCE 700 1- Selvaraj Manickam Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut NATIONALLICENCE 700 1- Park Dae-Won Division of Chemical and Biomolecular Engineering, Pusan National University, Jangjeon-dong, Gumjung-gu, 609-735, Busan, Republic of Korea aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 353-365 1878-5190 102:2<353 2011 102 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer