caa a22 4500 445388994 CHVBK 20180317143040.0 cr unu---uuuuu 170323e20110401xx s 000 0 eng 10.1007/s11144-011-0282-7 doi (NATIONALLICENCE)springer-10.1007/s11144-011-0282-7 Synthesis, characterization and catalytic activity of neat and alumina supported trans -(diaqua)( N , N -ethylene-bis-salicylamide)chromium(III): a comparative study [Elektronische Daten] [N. Das, P. Satapathy, S. Dash, P. Mohanty] A new CrIII-Schiff base complex of N,N′-ethylene-bis-salicylamide (Salm), supported on acidic alumina, was characterized by chemical and spectral (UV-Vis-DRS and FT-IR) analyses. The comparative catalytic activity of the neat and supported metal complex was evaluated using H2O2 decomposition as the model reaction at varying H2O2 concentration and amount of catalyst which showed a higher activity for the supported metal complex. A preliminary study showed that the supported CrIII(Salm) was also active for the oxidation of phenol using H2O2 as oxidant leading to catechol (selectivity~62%) and hydroquinone (selectivity~32%) as the major products. Akadémiai Kiadó, Budapest, Hungary, 2011 Chromium(III) nationallicence Schiff's base complex nationallicence Peroxide decomposition nationallicence Alumina support nationallicence Phenol oxidation nationallicence Das N. P.G. Department of Chemistry, North Orissa University, 757 003, Takatpur, Baripada, Orissa, India aut Satapathy P. P.G. Department of Chemistry, North Orissa University, 757 003, Takatpur, Baripada, Orissa, India aut Dash S. P. G. Department of Chemistry, Utkal University, 751 004, Bhubaneswar, Orissa, India aut Mohanty P. P. G. Department of Chemistry, Utkal University, 751 004, Bhubaneswar, Orissa, India aut Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 367-376 1878-5190 102:2<367 2011 102 11144 https://doi.org/10.1007/s11144-011-0282-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-011-0282-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Das N. P.G. Department of Chemistry, North Orissa University, 757 003, Takatpur, Baripada, Orissa, India aut NATIONALLICENCE 700 1- Satapathy P. P.G. Department of Chemistry, North Orissa University, 757 003, Takatpur, Baripada, Orissa, India aut NATIONALLICENCE 700 1- Dash S. P. G. Department of Chemistry, Utkal University, 751 004, Bhubaneswar, Orissa, India aut NATIONALLICENCE 700 1- Mohanty P. P. G. Department of Chemistry, Utkal University, 751 004, Bhubaneswar, Orissa, India aut NATIONALLICENCE 773 0- Reaction Kinetics, Mechanisms and Catalysis Springer Netherlands 102/2(2011-04-01), 367-376 1878-5190 102:2<367 2011 102 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer