caa a22 4500 445844248 CHVBK 20180317145353.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s11085-011-9260-8 doi (NATIONALLICENCE)springer-10.1007/s11085-011-9260-8 Accelerated Oxidation of V2O5-Deposited Copper [Elektronische Daten] [A. Klimashin, V. Belousov] The accelerated-oxidation kinetics of V2O5-deposited copper were studied in the temperature range 560-800°C in air. The accelerated oxidation followed the parabolic-rate law, indicating that the process was diffusion-controlled. Oxygen diffusion along liquid channels in the oxide scale was inferred to be the rate-limiting step in the overall mechanism. The parabolic-rate constant increased from 3.4×10−6 to 1.6×10−5kg2m−4s−1 with increasing the deposit mass from 0.075 to 0.225kgm−2 at 700°C. Springer Science+Business Media, LLC, 2011 Copper nationallicence Vanadium oxide nationallicence Accelerated corrosion nationallicence Kinetics nationallicence Diffusion nationallicence Klimashin A. A.A. Baikov Institute of Metallurgy and Materials, Russian Academy of Sciences, 49 Leninskii Pr., 119991, Moscow, Russia aut Belousov V. A.A. Baikov Institute of Metallurgy and Materials, Russian Academy of Sciences, 49 Leninskii Pr., 119991, Moscow, Russia aut Oxidation of Metals Springer-Verlag 76/5-6(2011-12-01), 359-366 0030-770X 76:5-6<359 2011 76 11085 https://doi.org/10.1007/s11085-011-9260-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11085-011-9260-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Klimashin A. A.A. Baikov Institute of Metallurgy and Materials, Russian Academy of Sciences, 49 Leninskii Pr., 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Belousov V. A.A. Baikov Institute of Metallurgy and Materials, Russian Academy of Sciences, 49 Leninskii Pr., 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Oxidation of Metals Springer-Verlag 76/5-6(2011-12-01), 359-366 0030-770X 76:5-6<359 2011 76 11085 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer