caa a22 4500 445850744 CHVBK 20180317145412.0 cr unu---uuuuu 170323e20111001xx s 000 0 eng 10.1134/S0040579511040129 doi (NATIONALLICENCE)springer-10.1134/S0040579511040129 Popov V. Kutaladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent'eva 1, 630090, Novosibirsk, Russia aut Evolution of reactive polymer structures in a field of mechanical, entropic, and diffusion forces [Elektronische Daten] [V. Popov] The physicochemical foundations of the evolution of reactive polymer structures in a field of mechanical, entropic (elastic), and diffusion forces are considered within the framework of locally nonequilibrium thermodynamics. It is theoretically shown how the stochastic process of the formation of molecular, nano-, and microscale structures can be controlled with the use of the thermodynamic state parameters by kinetic and diffusion relaxation mechanisms. It is established that the known "nanoreactor” effect is caused by the fact thatthe activation energy of a particle ensemble organized by the considered forces into these structural dimensions is much low than the energy barrier of a microsystem. Pleiades Publishing, Ltd., 2011 Theoretical Foundations of Chemical Engineering SP MAIK Nauka/Interperiodica 45/5(2011-10-01), 610-618 0040-5795 45:5<610 2011 45 11236 https://doi.org/10.1134/S0040579511040129 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1134/S0040579511040129 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Popov V. Kutaladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent'eva 1, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Theoretical Foundations of Chemical Engineering SP MAIK Nauka/Interperiodica 45/5(2011-10-01), 610-618 0040-5795 45:5<610 2011 45 11236 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer