caa a22 4500 445867515 CHVBK 20180317145502.0 cr unu---uuuuu 170323e20111101xx s 000 0 eng 10.1140/epjd/e2011-20009-4 doi (NATIONALLICENCE)springer-10.1140/epjd/e2011-20009-4 Scattering of Stark-decelerated OH radicals with rare-gas atoms [Elektronische Daten] [L. Scharfenberg, K. Gubbels, M. Kirste, G. Groenenboom, A. van der Avoird, G. Meijer, S. van de Meerakker] We present a combined experimental and theoretical study on the rotationally inelastic scattering of OH (X2Π3/2, J = 3/2, f) radicals with the collision partners He, Ne, Ar, Kr, Xe, and D2 as a function of the collision energy between ∼70 cm−1 and 400 cm−1. The OH radicals are state selected and velocity tuned prior to the collision using a Stark decelerator, and field-free parity-resolved state-to-state inelastic relative scattering cross sections are measured in a crossed molecular beam configuration. For all OH-rare gas atom systems excellent agreement is obtained with the cross sections predicted by coupled channel scattering calculations based on accurate ab initio potential energy surfaces. This series of experiments complements recent studies on the scattering of OH radicals with Xe [J.J. Gilijamse, S. Hoekstra, S.Y.T. van de Meerakker, G.C. Groenenboom, G. Meijer, Science 313, 1617 (2006)], Ar [L. Scharfenberg, J. Kłos, P.J. Dagdigian, M.H. Alexander, G. Meijer, S.Y.T. van de Meerakker, Phys. Chem. Chem. Phys. 12, 10660 (2010)], He, and D2 [M. Kirste, L. Scharfenberg, J. Kłos, F. Lique, M.H. Alexander, G. Meijer, S.Y.T. van de Meerakker, Phys. Rev. A 82, 042717 (2010)]. A comparison of the relative scattering cross sections for this set of collision partners reveals interesting trends in the scattering behavior. EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg, 2011 Scharfenberg L. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut Gubbels K. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut Kirste M. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut Groenenboom G. Institute for Molecules and Materials, Radboud Universiteit Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen, The Netherlands aut van der Avoird A. Institute for Molecules and Materials, Radboud Universiteit Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen, The Netherlands aut Meijer G. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut van de Meerakker S. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut The European Physical Journal D Springer-Verlag 65/1-2(2011-11-01), 189-198 1434-6060 65:1-2<189 2011 65 10053 https://doi.org/10.1140/epjd/e2011-20009-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1140/epjd/e2011-20009-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Scharfenberg L. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut NATIONALLICENCE 700 1- Gubbels K. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut NATIONALLICENCE 700 1- Kirste M. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut NATIONALLICENCE 700 1- Groenenboom G. Institute for Molecules and Materials, Radboud Universiteit Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen, The Netherlands aut NATIONALLICENCE 700 1- van der Avoird A. Institute for Molecules and Materials, Radboud Universiteit Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen, The Netherlands aut NATIONALLICENCE 700 1- Meijer G. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut NATIONALLICENCE 700 1- van de Meerakker S. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195, Berlin, Germany aut NATIONALLICENCE 773 0- The European Physical Journal D Springer-Verlag 65/1-2(2011-11-01), 189-198 1434-6060 65:1-2<189 2011 65 10053 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer