caa a22 4500 445870605 CHVBK 20180317145510.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s10563-011-9112-1 doi (NATIONALLICENCE)springer-10.1007/s10563-011-9112-1 Synthesis of Acetoaldehyde, Acetic Acid, and Others by the Dehydrogenation and Oxidation of Ethanol [Elektronische Daten] [Takashi Takei, Norihiko Iguchi, Masatake Haruta] Following gradual shift of primary resources from fossil towards renewable ones in chemical industry, biomass based ethanol has been attracting growing interests as a fuel to replace gasoline and as a chemical feed stock to replace ethylene. This paper reviews major work reported in the last 10years for the production of acetaldehyde, acetic acid, and other related compounds from ethanol. At present acetic acid can be industrially produced more economically from methanol than from ethylene, the production of acetic acid from ethanol is not profitable. Acetaldehyde, which is more expensive than ethanol, can be selectively produced in gas phase by dehydrogenation over supported Cu catalysts and by oxidation with O2 over V and Mo based oxides. It is noteworthy that gold nanoparticles deposited on basic and acidic metal oxides are highly selective to acetaldehyde by oxidation with O2. Acetic acid can be produced in water solvent over Au catalysts supported on MgAl2O4 or on Cu doped NiO, while in gas phase over Mo-V-Nb mixed oxides combined with TiO2 colloids. Springer Science+Business Media, LLC, 2011 Ethanol nationallicence Acetaldehyde nationallicence Acetic acid nationallicence Ethyl acetate nationallicence Ethylene oxide nationallicence Gold catalysts nationallicence Copper catalysts nationallicence Mo or V based oxides nationallicence Takei Takashi Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut Iguchi Norihiko Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut Haruta Masatake Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut Catalysis Surveys from Asia Springer US; http://www.springer-ny.com 15/2(2011-06-01), 80-88 1571-1013 15:2<80 2011 15 10563 https://doi.org/10.1007/s10563-011-9112-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10563-011-9112-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Takei Takashi Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut NATIONALLICENCE 700 1- Iguchi Norihiko Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut NATIONALLICENCE 700 1- Haruta Masatake Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, 192-0397, Hachioji, Tokyo, Japan aut NATIONALLICENCE 773 0- Catalysis Surveys from Asia Springer US; http://www.springer-ny.com 15/2(2011-06-01), 80-88 1571-1013 15:2<80 2011 15 10563 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer