caa a22 4500 463162471 CHVBK 20180406164751.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10311-006-0090-x doi (NATIONALLICENCE)springer-10.1007/s10311-006-0090-x Influence of ozone on the sampling and storage of volatile organic compounds in canisters [Elektronische Daten] [Fabienne Palluau, Philippe Mirabel, Maurice Millet] A dynamic dilution system was used for the study of the influence of ozone on the sampling and storage of volatile organic compounds (VOCs) at 0, 4, 7 and 14 days in "TO-Can” canisters at two ozone concentrations, 60 and 150ppbv. Among the 31 ozone precursors VOCs, a representative mixture containing five alkenes, five aromatics, acetylene and 1,3 butadiene was selected using the Clausius-Clapeyron equation. Here, we demonstrate that the presence of ozone have no influence on the concentrations of VOCs after 14 days storage period and consequently no problem of representativity of the sampling appears after 14 days of storage. The main explanation is the degradation of ozone in contact with deactivated walls of canisters. Springer-Verlag, 2006 "TO-Can” canisters nationallicence Ozone nationallicence Ozone precursors VOCs nationallicence Dynamic dilution system nationallicence Palluau Fabienne Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut Mirabel Philippe Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut Millet Maurice Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut Environmental Chemistry Letters Springer-Verlag 5/2(2007-05-01), 51-55 1610-3653 5:2<51 2007 5 10311 https://doi.org/10.1007/s10311-006-0090-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10311-006-0090-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Palluau Fabienne Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut NATIONALLICENCE 700 1- Mirabel Philippe Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut NATIONALLICENCE 700 1- Millet Maurice Laboratoire de Physico-Chimie de l'Atmosphère, Centre de Géochimie de la Surface (UMR 7517 CNRS-Université Louis Pasteur), 1 rue Blessig, F67084, Strasbourg Cedex, France aut NATIONALLICENCE 773 0- Environmental Chemistry Letters Springer-Verlag 5/2(2007-05-01), 51-55 1610-3653 5:2<51 2007 5 10311 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer