caa a22 4500 463184041 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10870-006-9152-y doi (NATIONALLICENCE)springer-10.1007/s10870-006-9152-y Synthesis and crystal structure of a copper coordination polymer [(Cu(btapo)2BrCH3OH)+Br−]n (btapo=1,3-bis(benzotriazol-1-yl) propan-2-ol) [Elektronische Daten] [Guo-Fang Zhang, Yin-Li Dou, Jiang-Bo She, Mai-Hua Yin] A new coordination polymer [(Cu(btapo)2BrCH3OH)+Br−]n (btapo = 1,3-bis(benzotria- zol-1-yl) propan-2-ol) was synthesized by the reaction of CuBr2 and btapo, a new ligand synthesized in our laboratory, in THF. Its structure was determined by single-crystal X-ray crystallography. It crystallizes in tetragonal I4(1)/a space group with the crystal cell parameters of a=11.987(9) Å, c=54.24(4) Å, V=7794(10) Å3, and Z=8. The crystal X-ray analysis shows that each copper atom is five-coordinated with a bromine atom and four nitrogen atoms from four ligands to form a slightly distorted square pyramid. Each ligand bridges two copper atoms to form a two-strand helical chain. The chains are further extended to a three-dimensional network by the hydrogen bonds between the hydroxyl groups and the bromine anions. Springer Science+Business Media, LLC, 2006 1,3-bis(benzotriazol-1-yl)propan-2-ol(btapo) nationallicence copper coordination polymer nationallicence crystal structure nationallicence Zhang Guo-Fang Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut Dou Yin-Li Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut She Jiang-Bo Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut Yin Mai-Hua Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/1(2007-01-01), 63-67 1074-1542 37:1<63 2007 37 10870 https://doi.org/10.1007/s10870-006-9152-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9152-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhang Guo-Fang Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut NATIONALLICENCE 700 1- Dou Yin-Li Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut NATIONALLICENCE 700 1- She Jiang-Bo Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut NATIONALLICENCE 700 1- Yin Mai-Hua Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, P. R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/1(2007-01-01), 63-67 1074-1542 37:1<63 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer