caa a22 4500 46318405X CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10870-007-9187-8 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9187-8 Yang De- Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, 721007, Baoji, P.R. China aut Synthesis, characterization and crystal structure of a mononuclear iron(III) complex derived from 4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol [Elektronische Daten] [De- Yang] A nitrate salt of bis[4-bromo-2-(pyridin-2-ylmethyliminomethyl)phenolato]iron(III), [Fe(C13H10BrN2O)2].NO3, has been obtained and characterized by elemental analysis and X-ray single crystal determination. The complex crystallizes in the tetragonal space group P42/n with unit cell dimensions a=b=17.608(3) Å, c=17.199(3) Å, V=5332.4(15) Å3, Z=8, R 1=0.0444 and wR2=0.0902. The complex consists of a [Fe(C13H10BrN2O)2]+ cation and a nitrate anion. The Fe atom in the cation is six-coordinated in an octahedral geometry. In the crystal structure, molecules are linked through weak C-H⋯O intermolecular hydrogen bonds, forming chains running along the c axis. Springer Science+Business Media, LLC, 2007 Schiff base nationallicence iron(III) nationallicence synthesis nationallicence crystal structure nationallicence Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 429-432 1074-1542 37:6<429 2007 37 10870 https://doi.org/10.1007/s10870-007-9187-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9187-8 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Yang De- Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, 721007, Baoji, P.R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 429-432 1074-1542 37:6<429 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer