caa a22 4500 463184092 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10870-006-9166-5 doi (NATIONALLICENCE)springer-10.1007/s10870-006-9166-5 Syntheses and crystal structures of an organometallic thiosemicarbazone and an organometallic enehydrazide [Elektronische Daten] [Yao-Cheng Shi, Hong-Jian Cheng, Chun-Xia Sui, Bei-Bei Zhu] Reactions of ferrocenoylacetone with thiosemicarbazide and isonicotinic acid hydrazide generate an organometallic thiosemicarbazone 1 and enehydrazide 2, respectively. The complexes 1 and 2, which can be formulated as [C5H5FeC5H4C(O)CH2C(=NNHCSNH2)CH3] and [C5H5FeC5H4C(O)CH=C(NHNHCOC5H4N-4)CH3], have been characterized by elemental analyses, IR, NMR, UV and were structurally characterized by single-crystal X-ray crystallography. Complex 1 (C15H17FeN3OS) crystallizes in the monoclinic space group P21/c, with lattice constants: a=13.939(3)Å, b=8.2600(17)Å, c=13.176(3)Å, β=94.83(3)°, V=1511.7(6)Å3, Z=4, D c=1.508gcm−3, F(000)=712, R 1=0.0602, wR 2=0.1526. Two intermolecular hydrogen bonds N-H···S (N···S = 3.356(8) and 3.499(7)Å, N-H···S=168 and 170°) form a chain in the [010] direction. The intermolecular hydrogen bond C-H···O (C···O=3.432(10)Å, C-H···O=151°) leads to a [010] double-chain through each unit cell. The intermolecular hydrogen bond C-H···O (C···O=3.359(10)Å, C-H···O=173°) makes the [010] double-chain pack along the c axis to result in a two-dimensional network. Complex 2 (C20H19FeN3O2) crystallizes in the monoclinic space group P21/c, with lattice constants: a=14.091(2)Å, b=10.024(2)Å, c=13.806(2)Å, β=112.41(2)°, V=1802.8(6)Å3, Z=4, D c=1.434gcm−3, F(000)=808, R 1=0.0576, wR 2=0.1593. The strong intramolecular hydrogen bond N-H···O from the enamine N atom and carbonyl O atom stabilizes the enehydrazide. The intermolecular hydrogen bonds N-H···O and C-H···O (N···O=2.906(6)Å, N-H···O=155° C···O=3.364(6)Å, C-H···O=153°) generate a [010] chain. The intermolecular hydrogen bond N-H···O (N···O=2.989(6)Å, N-H···O=128°) forms a [010] double-chain through each unit cell. The π···π stacking interation involving the pyridyl groups makes the [010] double-chain pack along the c axis to lead to a two-dimensional network. Springer Science+Business Media, LLC, 2007 Ferrocenoylacetone nationallicence hydrazide nationallicence thiosemicarbazone nationallicence enehydrazide nationallicence X-ray crystallography nationallicence Shi Yao-Cheng School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut Cheng Hong-Jian School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut Sui Chun-Xia School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut Zhu Bei-Bei School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 399-405 1074-1542 37:6<399 2007 37 10870 https://doi.org/10.1007/s10870-006-9166-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9166-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Shi Yao-Cheng School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut NATIONALLICENCE 700 1- Cheng Hong-Jian School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut NATIONALLICENCE 700 1- Sui Chun-Xia School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut NATIONALLICENCE 700 1- Zhu Bei-Bei School of Chemistry, Yangzhou University, 225002, Yangzhou, P.R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 399-405 1074-1542 37:6<399 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer