caa a22 4500 463184106 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10870-007-9185-x doi (NATIONALLICENCE)springer-10.1007/s10870-007-9185-x Synthesis, characterization and crystal structure of bis{2-methoxy-6-[(2-diethylaminoethylimino)methyl]phenolato}thiocyanatocobalt(III) perchlorate [Elektronische Daten] [San-Jun Peng, Zhong-Lu You] Brown block-shaped crystals of bis{2-methoxy-6-[(2-diethylaminoethylimino)methyl]phenolato}thiocyanatocobalt(III) perchlorate, the first cobalt(III) complex derived from the Schiff base ligand HL, [CoIII(L)(HL)(NCS)].ClO4 (HL=2-methoxy-6-[(2-diethylaminoethylimino)methyl]phenol) have been obtained and characterized by elemental analysis and X-ray single crystal determination. The complex crystallizes in the monoclinic space group P21/c with unit cell dimensions a=16.087(3) Å, b=12.354(3) Å, c=16.762(3) Å, β=93.77(3)°, V=3324.1(12) Å3, Z=4, R 1=0.0741 and wR2=0.1366. X-ray structure determination revealed that the complex consists of a [CoIII(L)(HL)(NCS)]+ cation and a disordered perchlorate anion. The Co atom in the cation is six-coordinate in an octahedral coordination. In the crystal structure, the perchlorate anions are linked to the cations through intermolecular C-H⋯O hydrogen bonds, forming zigzag chains running along the caxis. It is the first cobalt(III) complex derived from the Schiff base ligand HL. Springer Science+Business Media, LLC, 2007 Schiff base nationallicence cobalt(III) complex nationallicence crystal structure nationallicence hydrogen bonds nationallicence crystallography nationallicence Peng San-Jun Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology, 410076, Changsha, P. R. China aut You Zhong-Lu Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology, 410076, Changsha, P. R. China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 415-419 1074-1542 37:6<415 2007 37 10870 https://doi.org/10.1007/s10870-007-9185-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9185-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Peng San-Jun Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology, 410076, Changsha, P. R. China aut NATIONALLICENCE 700 1- You Zhong-Lu Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology, 410076, Changsha, P. R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/6(2007-06-01), 415-419 1074-1542 37:6<415 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer