caa a22 4500 463184165 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10870-007-9227-4 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9227-4 Synthesis and Crystal Structure of the Salt [PPN+]2[Cu2I2Cl2]2− [Elektronische Daten] [Andrey Yakovenko, Tatiana Timofeeva, Mikhail Antipin] The synthesis of the PPN (PPN=Ph3P=N=PPh3) salt of di-μ-iodo-dichlorocuprate (I) anion [Cu2I2Cl2]2− is described and the crystal and molecular structures of this compound are reported. It was found that the compound has the formula [PPN]2[Cu2I2Cl2]0.7[Cu2I4]0.3 (3). Compound 3 crystallizes in an orthorhombic crystal system, space group Pbca, with a=19.654(3), b=16.130(2), c=20.108(3)Å, V=6374.3(16)Å3 and Z=4. The crystal contains 70% [Cu2I2Cl2]2− anions and 30% [Cu2I4]2− anions. This was also confirmed by MSES spectroscopy. The anion [Cu2I2Cl2]2− is planar and the Cu atoms have a trigonal planar configuration. Graphical abstract: Synthesis and Crystal Structure of the Salt [PPN + ] 2 [Cu 2 I 2 Cl 2 ] 2− Andrey A. Yakovenko, Tatiana V. Timofeeva and Mikhail Yu. Antipin The title compound was synthesized and structurally investigated. The crystal contains 70% [Cu2I2Cl2]2− anions and 30% [Cu2I4]2− anions. This was confirmed by MS ES spectroscopy. Springer Science+Business Media, LLC, 2007 Di- μ -halo-dihalocuprates nationallicence PPN salts nationallicence Disorder nationallicence Crystal structure nationallicence Yakovenko Andrey Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut Timofeeva Tatiana Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut Antipin Mikhail Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 645-649 1074-1542 37:9<645 2007 37 10870 https://doi.org/10.1007/s10870-007-9227-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9227-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yakovenko Andrey Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut NATIONALLICENCE 700 1- Timofeeva Tatiana Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut NATIONALLICENCE 700 1- Antipin Mikhail Department of Natural Sciences, New Mexico Highlands University, 87701, Las Vegas, NM, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 645-649 1074-1542 37:9<645 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer