caa a22 4500 46318419X CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10870-007-9219-4 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9219-4 Isolation and Crystal Structure of [Cu(L1)(O2CH)](ClO4)·H2O: Hydrolysis of DMF ( N , N -Dimethylformamide) by a Copper(II) Tetraazamacrocycle [Elektronische Daten] [Ju Kim, Jungyun Roh, Alan Lough] The tetraazamacrocyclic copper(II) complex, [Cu(L)](ClO4)2 (L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14.4.01.18.07.12]docosane), hydrolyzes DMF at room temperature. The formate anion which is one of the hydrolyzed species of DMF coordinates to the copper(II) ion to form [Cu(L1)(O2CH)](ClO4)·H2O (1). The crystals of the complex 1 were isolated and structurally characterized by a combination of analytical, spectroscopic, and crystallographic methods. In 1, the macrocyclic ligand contains two trans fused cyclohexane rings, and the coordination geometry about the copper(II) ion adopts a square pyramid with four equatorial nitrogen atoms from the macrocycle and an oxygen atom from the formato ligand with an uncoordinated perchlorate ion. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Tetraazamacrocycle nationallicence Amide hydrolysis nationallicence Copper(II) complex nationallicence Kim Ju Department of Chemistry, Pukyong National University, 608 737, Pusan, Korea aut Roh Jungyun Department of Chemistry, Pukyong National University, 608 737, Pusan, Korea aut Lough Alan Department of Chemistry, University of Toronto, M5S 3H6, Toronto, ON, Canada aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 615-618 1074-1542 37:9<615 2007 37 10870 https://doi.org/10.1007/s10870-007-9219-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9219-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kim Ju Department of Chemistry, Pukyong National University, 608 737, Pusan, Korea aut NATIONALLICENCE 700 1- Roh Jungyun Department of Chemistry, Pukyong National University, 608 737, Pusan, Korea aut NATIONALLICENCE 700 1- Lough Alan Department of Chemistry, University of Toronto, M5S 3H6, Toronto, ON, Canada aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 615-618 1074-1542 37:9<615 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer