caa a22 4500 46318422X CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10870-007-9220-y doi (NATIONALLICENCE)springer-10.1007/s10870-007-9220-y Synthesis and Crystal Structure of Pivalamidate-Bridged Trinuclear Platinum-Copper Complex with a Linear Pt-Cu-Pt Core [Elektronische Daten] [Chao Chen, Huayu Qiu, Fenghui Liu, Wanzhi Chen] The heterotrimetallic complex [Cu{trans-Pt(NH3)2(NHCOtBu)2}2](NO3)2 was synthesized and structurally characterized by X-ray crystallography. The cationic complex consists two trans-[Pt(NH3)2(NHCOtBu)2] units and one Cu2+ ion, which are linearly held together by four bridging pivalamidate ligands. The compound crystallizes in the monoclinic space group P21/c with a=13.18(1)Å, b=13.12(1)Å, c=21.38(2)Å, β=116.88(3)°Å, V=3674(5)Å3, and Z=4. The trimeric Pt-Cu-Pt cation further aggregates into a dimer of trimer via a weak Pt···Pt interaction. Graphical abstract: Synthesis and crystal structure of pivalamidate-bridged trinuclear platinum-copper complex with a linear Pt-Cu-Pt core Chao Chen, Huayu Qiu*, Fenghui Liu and Wanzhi Chen* A heterotrimetallic complex [Cu{trans-Pt(NH3)2(NHCOtBu)2}2](NO3)2 was synthesized and structurally characterized by X-ray crystallography. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Platinum nationallicence Copper nationallicence Pivalamidate nationallicence Chen Chao Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, 310012, Hangzhou, P.R. China aut Qiu Huayu Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, 310012, Hangzhou, P.R. China aut Liu Fenghui Department of Chemistry, Zhejiang University, Xixi Campus, 310023, Hangzhou, Zhejiang, P.R. China aut Chen Wanzhi Department of Chemistry, Zhejiang University, Xixi Campus, 310023, Hangzhou, Zhejiang, P.R. China aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 619-622 1074-1542 37:9<619 2007 37 10870 https://doi.org/10.1007/s10870-007-9220-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9220-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chen Chao Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, 310012, Hangzhou, P.R. China aut NATIONALLICENCE 700 1- Qiu Huayu Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, 310012, Hangzhou, P.R. China aut NATIONALLICENCE 700 1- Liu Fenghui Department of Chemistry, Zhejiang University, Xixi Campus, 310023, Hangzhou, Zhejiang, P.R. China aut NATIONALLICENCE 700 1- Chen Wanzhi Department of Chemistry, Zhejiang University, Xixi Campus, 310023, Hangzhou, Zhejiang, P.R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/9(2007-09-01), 619-622 1074-1542 37:9<619 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer