caa a22 4500 463184238 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10870-007-9191-z doi (NATIONALLICENCE)springer-10.1007/s10870-007-9191-z The Simultaneous Presence of Different Varieties of Intermolecular Hydrogen Bonds in a New Layer-Type Anionic Host Lattice Built of Thiourea, Fumaric Acid and Fumarate Anion [Elektronische Daten] [Qi Li, Bin Li, Yuan Yang, Chi-Keung Lam, Thomas Mak] A new inclusion complex (n-C4H9)4N+C4H3O 4 − ·C4H4O4·(NH2)2CS has been prepared and characterized by X-ray crystallography. Crystal data: space group P $$ \overline 1 $$ , a=8.799(2)Å, b=9.590(1)Å, c=18.684(4) Å, α=89.63(1)°, β=79.56(1)°, γ=79.74(1)°, V=1525.2(5) Å3, Z=2, R 1=0.0562 and wR=0.1033. In the title compound, thiourea molecules, fumaric acid and fumarate anions are joined together by typical O-H···O, N-H···O and N-H···S, plus weak C-H···O and C-H···S, hydrogen bonds to generate a hydrogen-bonded layer corresponding to the (100) family of planes. The tetra-n-butylammonium cations are orderly arranged in a sandwich-like packing mode between the stacked layers. The simultaneous presence of different varieties of intermolecular hydrogen bonds is an interesting feature of the title compound. Springer Science+Business Media, LLC, 2007 Fumaric acid nationallicence Thiourea nationallicence Hydrogen bonds nationallicence Inclusion compound nationallicence Crystal structure nationallicence Li Qi College of Chemistry, Beijing Normal University, 100875, Beijing, China aut Li Bin College of Chemistry, Beijing Normal University, 100875, Beijing, China aut Yang Yuan College of Chemistry, Beijing Normal University, 100875, Beijing, China aut Lam Chi-Keung Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China aut Mak Thomas Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 451-456 1074-1542 37:7<451 2007 37 10870 https://doi.org/10.1007/s10870-007-9191-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9191-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Li Qi College of Chemistry, Beijing Normal University, 100875, Beijing, China aut NATIONALLICENCE 700 1- Li Bin College of Chemistry, Beijing Normal University, 100875, Beijing, China aut NATIONALLICENCE 700 1- Yang Yuan College of Chemistry, Beijing Normal University, 100875, Beijing, China aut NATIONALLICENCE 700 1- Lam Chi-Keung Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China aut NATIONALLICENCE 700 1- Mak Thomas Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 451-456 1074-1542 37:7<451 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer