caa a22 4500 463184262 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10870-007-9189-6 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9189-6 Hydrogen-Bonding Interactions in the Crystal Structure of Bis( N -propyl- N -(2-hydroxyethyl)dithiocarbamato- S , S ′)nickel(II): Ni[S2CN(nPr)(CH2CH2OH)]2 [Elektronische Daten] [Edward Tiekink, James Wardell, Solange Wardell] Two independent molecules of Ni(S2CN(Pr)CH2CH2OH)2, each located about a center of inversion, comprise the asymmetric unit. The molecules differ from each other in terms of the relative orientation of the terminal hydroxyl groups. A square planar geometry is found for each nickel atom defined by four sulfur atoms derived from two symmetrically chelating dithiocarbamate ligands. The crystal packing is dominated by O-H···O interactions that lead to extensive cross linking in all directions. The compound crystallizes in the triclinic space group P-1 with a=6.4008(11)Å, b=11.480(2)Å, c=12.517(2)Å, α=88.021(2)°, β=82.491(2)°, γ=89.986(2)°, and Z=2. Springer Science+Business Media, LLC, 2007 Nickel nationallicence Dithiocarbamate nationallicence Metal complex nationallicence Hydrogen-bonding nationallicence Tiekink Edward Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, 78249-0698, San Antonio, TX, USA aut Wardell James Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, 78249-0698, San Antonio, TX, USA aut Wardell Solange FioCruz - Fundação Oswaldo Cruz, Instituto de Tecnologia em Fármacos - FarManguinhos, Rua Sizenando Nabuco, 100, Manguinhos, 21041-250, Rio de Janeiro, RJ, Brazil aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 439-443 1074-1542 37:7<439 2007 37 10870 https://doi.org/10.1007/s10870-007-9189-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9189-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Tiekink Edward Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, 78249-0698, San Antonio, TX, USA aut NATIONALLICENCE 700 1- Wardell James Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, 78249-0698, San Antonio, TX, USA aut NATIONALLICENCE 700 1- Wardell Solange FioCruz - Fundação Oswaldo Cruz, Instituto de Tecnologia em Fármacos - FarManguinhos, Rua Sizenando Nabuco, 100, Manguinhos, 21041-250, Rio de Janeiro, RJ, Brazil aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 439-443 1074-1542 37:7<439 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer