caa a22 4500 463184270 CHVBK 20180406164847.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10870-007-9192-y doi (NATIONALLICENCE)springer-10.1007/s10870-007-9192-y Synthesis and Crystal Structure of μ-oxo-bis[(octaethyloxoporphinato)iron(III)] Tetrafluoroborate [Elektronische Daten] [Mozhgan Khorasani-Motlagh, Nasser Safari, Hamid Khavasi, Meissam Noroozifar, Hashem Shahroosvand, Mahtab Biabani] Exposure of dichloromethane solution of [OEOPFe(BF4)], where OEOP is the monoanion of octaethyloxoporphyrin, to dioxygen results in its transformation into the μ-oxo bridged compound, [(OEOPFe)2O)](BF4)2. The molecular structure of the title compound, [(OEOPFe)2O](BF4)2, was determined by single-crystal X-ray diffraction. It contains a binuclear centrosymmetric [(OEOPFe)2O]2+ cation (the bridging O atom lies on an inversion centre) and two tetrafluoroborate anions. The Fe atom is five-coordinate to four N atoms of the porphyrin ring and to one bridging O atom. The compound is characterized by an average Fe-N bond length of 2.064Å. The Fe-O bond distance is 1.7665(11)Å and the Fe-O-Fe bond angle is 180.0° and the two porphyrin rings are parallel. Crystal data: crystal system, monoclinic, a=8.867(3), b=26.104(9), c=15.748(6)Å, β=105.40(3)°, space group, P21/c, V=3514(2)Å3, Z=2. Springer Science+Business Media, LLC, 2007 Verdoheme nationallicence Tetrafluoroborate anions nationallicence μ-oxo bridged compound nationallicence Octaethyloxoporphyrin nationallicence Khorasani-Motlagh Mozhgan Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut Safari Nasser Chemistry Department, University of Shahid Beheshti, Tehran, Iran aut Khavasi Hamid Chemistry Department, University of Shahid Beheshti, Tehran, Iran aut Noroozifar Meissam Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut Shahroosvand Hashem Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut Biabani Mahtab Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 457-461 1074-1542 37:7<457 2007 37 10870 https://doi.org/10.1007/s10870-007-9192-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9192-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Khorasani-Motlagh Mozhgan Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut NATIONALLICENCE 700 1- Safari Nasser Chemistry Department, University of Shahid Beheshti, Tehran, Iran aut NATIONALLICENCE 700 1- Khavasi Hamid Chemistry Department, University of Shahid Beheshti, Tehran, Iran aut NATIONALLICENCE 700 1- Noroozifar Meissam Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut NATIONALLICENCE 700 1- Shahroosvand Hashem Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut NATIONALLICENCE 700 1- Biabani Mahtab Chemistry Department, University of Sistan & Baluchestan, P.O. Box 98155-147, Zahedan, Iran aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 457-461 1074-1542 37:7<457 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer