caa a22 4500 463184327 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10870-007-9203-z doi (NATIONALLICENCE)springer-10.1007/s10870-007-9203-z A Novel Three Dimensional Organic-Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium pyromellitate, [VIV 2O2(H2O)2(C6H2(COO)4)] [Elektronische Daten] [Sabri Cevik, Mehmet Poyraz, Musa Sarı, Orhan Büyükgüngör] The hydrothermal reaction of a mixture of VOSO4·xH2O, 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) and 0.1M H2SO4 for 72h at 160°C gives blue needle like crystals of [VIV 2O2(H2O)2(C6H2(COO)4)] in 30% yield. The compound has a porous 3-D extended network structure having a rigid architecture which is held together by the multidentate functionalities of 1,2,4,5-benzenetetracarboxylate ligand. Crystal data for the compound: monoclinic space group C 2/c (No:15), a=11.756(5)Å, b=9.645(3)Å, c=11.822(7)Å, β=107.10(4)°, Z=8. The compound constitutes the first example of a fully reduced oxovanadium based solid incorporating the organic ligand. This article consists of synthesis, crystal structure and characterization of [VIV 2O2(H2O)2(C6H2(COO)4)]. Springer Science+Business Media, LLC, 2007 Organic-inorganic hybrid composites nationallicence Synthesis and design nationallicence Hydrothermal synthesis nationallicence Pyromellitate nationallicence Reduced oxovanadium nationallicence Structure and characterization nationallicence Cevik Sabri Department of Chemistry, Science and Literature Faculty, Afyon Kocatepe University, ANS Kampusu, Fen Edebiyat Fakultesi, Kimya Bolumu, 03200, Afyonkarahisar, Turkey aut Poyraz Mehmet Department of Chemistry, Science and Literature Faculty, Afyon Kocatepe University, ANS Kampusu, Fen Edebiyat Fakultesi, Kimya Bolumu, 03200, Afyonkarahisar, Turkey aut Sarı Musa Education Faculty, Department of Physics Education, Gazi University, 06500, Besevler-Ankara, Turkey aut Büyükgüngör Orhan Department of Physics, Science and Literature Faculty, Ondokuz Mayıs University, 55139, Kurupelit-Samsun, Turkey aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 497-502 1074-1542 37:7<497 2007 37 10870 https://doi.org/10.1007/s10870-007-9203-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9203-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Cevik Sabri Department of Chemistry, Science and Literature Faculty, Afyon Kocatepe University, ANS Kampusu, Fen Edebiyat Fakultesi, Kimya Bolumu, 03200, Afyonkarahisar, Turkey aut NATIONALLICENCE 700 1- Poyraz Mehmet Department of Chemistry, Science and Literature Faculty, Afyon Kocatepe University, ANS Kampusu, Fen Edebiyat Fakultesi, Kimya Bolumu, 03200, Afyonkarahisar, Turkey aut NATIONALLICENCE 700 1- Sarı Musa Education Faculty, Department of Physics Education, Gazi University, 06500, Besevler-Ankara, Turkey aut NATIONALLICENCE 700 1- Büyükgüngör Orhan Department of Physics, Science and Literature Faculty, Ondokuz Mayıs University, 55139, Kurupelit-Samsun, Turkey aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/7(2007-07-01), 497-502 1074-1542 37:7<497 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer