caa a22 4500 463184386 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10870-007-9243-4 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9243-4 Synthesis and Crystal Structure of the Fluorite-Related Ruthenate, Trilanthanum Ruthenium Septaoxide La3RuO7 [Elektronische Daten] [William Gemmill, Mark Smith, Hans-Conrad zur Loye] Single crystals of the lanthanum-containing ruthenate, trilanthanum ruthenium septaoxide, La3RuO7, were prepared via high-temperature flux growth and structurally characterized by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Cmcm with a=11.2077(6)Å, b=7.4531(4)Å, and c=7.6042(4)Å and is a member of a well-known family of compounds with the general formula Ln3MO7. Graphical abstract: Synthesis and crystal structure of the fluorite-related ruthenate, trilanthanum ruthenium septaoxide La 3 RuO 7 William R. Gemmill, Mark D. Smith and Hans-Conrad zur Loye* Single crystals of La3RuO7 were isolated from a high-temperature KCl flux and characterized by single crystal X-ray diffraction. A view of the crystal structure approximately along [001] of La3RuO7 and displacement ellipsoids drawn at 50% probability level. The vertex-sharing RuO6 octahedra are shown in blue, La3+ are shown in yellow, and O2− are shown in red. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Ruthenium oxide nationallicence La3RuO7 nationallicence Gemmill William Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut Smith Mark Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut zur Loye Hans-Conrad Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 793-795 1074-1542 37:12<793 2007 37 10870 https://doi.org/10.1007/s10870-007-9243-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9243-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gemmill William Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut NATIONALLICENCE 700 1- Smith Mark Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut NATIONALLICENCE 700 1- zur Loye Hans-Conrad Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, 29208, Columbia, SC, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 793-795 1074-1542 37:12<793 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer