caa a22 4500 463184408 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10870-007-9256-z doi (NATIONALLICENCE)springer-10.1007/s10870-007-9256-z Synthesis and Structural Characterization of Three Phenylsulfonyl Derivatives: Influence of Halogen Substituents on the Intermolecular Interactions [Elektronische Daten] [C. Castera, M. Crozet, M. Giorgi, P. Vanelle] Synthesis and X-ray structural determination of three halogenated nitroimidazo[1,2-a]pyridine phenylsulfonyl derivatives are reported. (2) is monoclinic P21/c with a=9.6679(1), b=11.3642(2), c=15.2189(2)Å, β=105.9053(7)°; (3) is triclinic P −1 with a=8.5556(2), b=13.1191(3), c=15.5132(4)Å, α=76.0110(8), β=89.1768(8), γ=78.953(2)°; (4) is monoclinic P21/c with a=15.3353(2), b=8.8621(2), c=11.4189(3)Å, β=90.9704(7)°. In the title compounds that differ by the nature and number of halogen substituents, the arylsulfonyl moieties are oriented differently relatively to the nitroimidazopyridine. Moreover non-classical intermolecular interactions are revealed by the X-ray analysis. Graphical Abstract: The X-ray structures of three halogenated nitroimidazo[1,2-a]pyridine phenylsulfonyl derivatives reveal different intermolecular interactions within the crystals. C. Castera, M. D. Crozet, M. Giorgi and P. Vanelle The X-ray structures of three halogenated nitroimidazo[1,2-a]pyridine phenylsulfonyl derivatives reveal different intermolecular interactions within the crystals. Synthesis and structural characterization of three phenylsulfonyl derivatives: influence of halogen substituents on the intermolecular interactions. C. Castera,1 M. D. Crozet,1 M. Giorgi,2 and P. Vanelle1* 1Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Université de la Méditerranée, Faculté de Pharmacie, 27 Boulevard Jean Moulin, 13385 Marseille cedex 5, France ; 2Spectropôle-RX, Université Paul Cézanne Aix-Marseille III, Faculté des Sciences et Techniques, Avenue Escadrille Normandie-Niemen, 13397 Marseille cedex 20, France. Springer Science+Business Media, LLC, 2007 Imidazo[1,2- a ]pyridine nationallicence Phenylsulfonyl derivatives nationallicence Crystal structure nationallicence Intermolecular contacts nationallicence Castera C. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut Crozet M. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut Giorgi M. Spectropôle-RX, Faculté des Sciences et Techniques, Université Paul Cézanne Aix-Marseille III, Avenue Escadrille Normandie-Niemen, 13397, Marseille Cedex 20, France aut Vanelle P. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 831-836 1074-1542 37:12<831 2007 37 10870 https://doi.org/10.1007/s10870-007-9256-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9256-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Castera C. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut NATIONALLICENCE 700 1- Crozet M. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut NATIONALLICENCE 700 1- Giorgi M. Spectropôle-RX, Faculté des Sciences et Techniques, Université Paul Cézanne Aix-Marseille III, Avenue Escadrille Normandie-Niemen, 13397, Marseille Cedex 20, France aut NATIONALLICENCE 700 1- Vanelle P. Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Faculté de Pharmacie, Université de la Méditerranée, 27 Boulevard Jean Moulin, 13385, Marseille Cedex 5, France aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 831-836 1074-1542 37:12<831 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer