caa a22 4500 463184432 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10870-007-9249-y doi (NATIONALLICENCE)springer-10.1007/s10870-007-9249-y Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag ( L )(CH3CN)](ClO4)}n [ L =5,6-dicyano-2,3-di(2-pyridyl)pyrazine] [Elektronische Daten] [Qian Gao, Ya-Bo Xie, Sha Chen, Dao Wang] The reaction of the organic ligand, 5,6-dicyano-2,3-di(2-pyridyl)pyrazine (L) with AgClO4, leads to the formation of a novel complex {[Ag(L)(CH3CN)](ClO4)}n 1, which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis (monoclinic system, space group P2(1)/n, with a=11.290(4), b=12.660(5), c=15.202(6) Å, β=90.141(6)°, V=13371(2) Å3 and Z=4). The crystal structure of complex consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and $${\text{ClO}}_{\text{4}}^{-}$$ anions. In the cation of 1, each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent L ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by L ligands which adopt N3-coordinated bridging mode to form a zig-zag chain. Index abstract: Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n [L=5,6-dicyano-2,3-di(2-pyridyl)pyrazine] Qian Gao, Ya-Bo Xie*, Sha Chen, and Dao Wang The crystal structure of complex {[Ag(L)(CH3CN)](ClO4)}n (L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine) consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and $${\text{ClO}}_{\text{4}}^{-}$$ anions. Each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by ligands which adopt N3-coordinated bridging mode to form a zig-zag chain. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Polymeric chain nationallicence Ag(I) complex nationallicence Gao Qian College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut Xie Ya-Bo College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut Chen Sha College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut Wang Dao College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 797-800 1074-1542 37:12<797 2007 37 10870 https://doi.org/10.1007/s10870-007-9249-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9249-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gao Qian College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut NATIONALLICENCE 700 1- Xie Ya-Bo College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut NATIONALLICENCE 700 1- Chen Sha College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut NATIONALLICENCE 700 1- Wang Dao College of Environmental and Energy Engineering, Beijing University of Technology, 100022, Beijing, China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/12(2007-12-01), 797-800 1074-1542 37:12<797 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer