caa a22 4500 463184491 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10870-006-9164-7 doi (NATIONALLICENCE)springer-10.1007/s10870-006-9164-7 Synthesis and crystal structure of Mn(II) and Zn(II) complexes with 1,3,5-tris(carboxymethoxyl)benzene ligand [Elektronische Daten] [Gang Wu, Yan Wang, Xiao-Feng Wang, Hiroyuki Kawaguchi, Wei-Yin Sun] Two complexes (H2bipy)[M2(TB)2(H2O)8]·5H2O (M=Mn 1, Zn 2) (bipy=4,4′-bipyridine, H3TB=1,3,5-tris(carboxymethoxyl)benzene) were synthesized by the reaction of the corresponding metal salt with ligand H3TB and 4,4′-bipy in an aqueous methanol solution at room temperature, respectively. Their structures were determined by single crystal X-ray diffraction analysis. Both complexes 1 and 2 crystallize in the triclinic space group $$P\bar 1$$ with the crystal parameters of 1: a=9.725(12)Å, b=10.651(13)Å, c=10.882(13)Å, α=91.72(2)°, β=96.41(2)°, γ=97.72(2)°, V=1109(2)Å3, Z=1 and 2: a=9.610(10)Å, b=10.55(2)Å, c=10.83(2)Å, α=91.60(4)°, β=95.32(2)°, γ=97.73(4)°, V=1082(3)Å3, Z=1. Complexes 1 and 2 have the same dinuclear structure, in which each metal atom is six coordinated with distorted octahedral geometry by two oxygen atoms from two different TB3− ligands and four ones from four coordinated water molecules. The dinuclear units are further linked by hydrogen bonding and π-π interactions to form the three-dimensional framework structure. Springer Science+Business Media, LLC, 2007 Mn(II) complex nationallicence Zn(II) complex nationallicence crystal structure nationallicence carboxylate ligand nationallicence π-π interactions nationallicence hydrogen bonds nationallicence Wu Gang State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut Wang Yan State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut Wang Xiao-Feng State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut Kawaguchi Hiroyuki Coordination Chemistry Laboratories, Institute for Molecular Science, 444-8585, Okazaki, Aichi, Japan aut Sun Wei-Yin State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/3(2007-03-01), 199-205 1074-1542 37:3<199 2007 37 10870 https://doi.org/10.1007/s10870-006-9164-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9164-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wu Gang State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut NATIONALLICENCE 700 1- Wang Yan State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut NATIONALLICENCE 700 1- Wang Xiao-Feng State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut NATIONALLICENCE 700 1- Kawaguchi Hiroyuki Coordination Chemistry Laboratories, Institute for Molecular Science, 444-8585, Okazaki, Aichi, Japan aut NATIONALLICENCE 700 1- Sun Wei-Yin State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, Nanjing University, 210093, Nanjing, China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/3(2007-03-01), 199-205 1074-1542 37:3<199 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer