caa a22 4500 463184580 CHVBK 20180406164848.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10870-007-9209-6 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9209-6 Synthesis, Crystal Structure and Spectral Properties of [Fe3(2,2′-bipy)6(ox)3]·12.25H2O Complex [Elektronische Daten] [Xuda Wang, Yunhe Xu, Xueyan Song, Licun Li, Daizheng Liao, Zonghui Jiang, Shiping Yan] A novel iron (II) complex of formula [Fe3(2,2′-bipy)6(ox)3]·12.25H2O (2,2′-bipy=2,2′-bipyridine, ox=oxalate) has been prepared and structurally characterized by X-ray crystallography. In the complex, the metal atoms are six-coordinated in distorted octahedral environment. In the complex [Fe(ox)3]4− anions and water molecules are linked together into 1D chain structure by hydrogen interaction. The red crystal of the complex is monoclinic, space group P21/c, with a=22.932(6)Å, b=13.715(4)Å, c=22.493(6)Å, β=93.177(5)°, and V=7063(3)Å3 with Z=4. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Iron(II) complex nationallicence 2,2′-bipy nationallicence Hydrogen bonding nationallicence Wang Xuda Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Xu Yunhe Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Song Xueyan Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Li Licun Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Liao Daizheng Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Jiang Zonghui Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Yan Shiping Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 651-654 1074-1542 37:10<651 2007 37 10870 https://doi.org/10.1007/s10870-007-9209-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9209-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Xuda Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Xu Yunhe Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Song Xueyan Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Li Licun Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Liao Daizheng Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Jiang Zonghui Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 700 1- Yan Shiping Department of Chemistry, Nankai University, 300071, Tianjin, P. R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 651-654 1074-1542 37:10<651 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer