caa a22 4500 463184602 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10870-007-9233-6 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9233-6 The Preparation, Characterization and X-ray Structural Analysis of Tetrakis[1,3-dimethyl-2(3H)-imidazoleselone]cadmium(II) Hexafluorophosphate [Elektronische Daten] [Daniel Williams, Bradley McKinney, Ben Baker, Kevin Gwaltney, Donald VanDerveer] A new compound, [Cd(dmise)4][PF6]2, has been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography (dmise=1,3-dimethyl-2(3H)-imidazoleselone). The title compounds crystallizes in orthorhombic space group P bcn with a=12.783(3), b=22.206(4), c=13.153(3)Å, V=3733.8(13) Å3, Z=4. The complex is a high melting, yellow water soluble 2:1 electrolyte solid that state has a flattened tetrahedral CdSe4 coordination geometry. To date this is the only structural study reported for a homoleptic selenourea complex of cadmium. Graphical abstract: The Preparation, characterization and X-ray structural analysis of Tetrakis[1,3-dimethyl-2(3H)-imidazoleselone]cadmium(II) hexafluorophosphate Daniel J. Williams, Bradley J. McKinney, Ben Baker, Kevin P. Gwaltney and Donald VanDerveer Tetrakis[1,3-dimethyl-2(3H)-imidazoleselone][PF6]2 is prepared in 82% yield by direct combination of cadmium acetate dihydrate, ammonium hexafluorophosphate, and the ligand in boiling acetonitrile. X-ray crystallography shows a structure with a distorted tetrahedral coordination sphere around the cadmium. This is the first report of a structural characterization of a homoleptic cadmium selenourea complex. Springer Science+Business Media, LLC, 2007 X-ray crystallography nationallicence Cadmium complex nationallicence Dimethylimidazoleselone nationallicence Homoleptic complex nationallicence Williams Daniel Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut McKinney Bradley Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut Baker Ben Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut Gwaltney Kevin Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut VanDerveer Donald Department of Chemistry, Clemson University, 29634, Clemson, SC, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 691-694 1074-1542 37:10<691 2007 37 10870 https://doi.org/10.1007/s10870-007-9233-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9233-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Williams Daniel Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut NATIONALLICENCE 700 1- McKinney Bradley Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut NATIONALLICENCE 700 1- Baker Ben Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut NATIONALLICENCE 700 1- Gwaltney Kevin Department of Chemistry and Biochemistry, Kennesaw State University, 30144, Kennesaw, GA, USA aut NATIONALLICENCE 700 1- VanDerveer Donald Department of Chemistry, Clemson University, 29634, Clemson, SC, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 691-694 1074-1542 37:10<691 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer