caa a22 4500 463184610 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10870-007-9232-7 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9232-7 Synthesis and Crystal Structure of a Cyano-Bridged Bimetallic Nickel(II)-Silver(I) Complex, [Ni(dmen)2{Ag(CN)2}2]·0.5H2O [Elektronische Daten] [Saeed Ahmad, Muhammad Monim-ul-Mehboob, Muhammad Altaf, Helen Stoeckli Evans, Rashid Mehmood] A cyano-bridged heteronuclear bimetallic complex [Ni(dmen)2{Ag(CN)2}2]·0.5H2O (dmen=N,N′-dimethylethylenediamine) has been prepared and characterized by IR spectroscopy and X-ray Crystallography. The compound crystallizes in the monoclinic space group P21/c. The crystal structure of the complex consists of two independent centrosymmetric trinuclear molecules made up of a [Ni(dmen)2] +2 unit linked to two [Ag(CN)2]− anions in a trans configuration. The trinuclear units are joined by hydrogen bonding to form irregular chains. Springer Science+Business Media, LLC, 2007 Coordination polymer nationallicence Crystal structure nationallicence Nickel(II) nationallicence Silver cyanide nationallicence Ahmad Saeed Department of Chemistry, University of Engineering and Technology, 54890, Lahore, Pakistan aut Monim-ul-Mehboob Muhammad Department of Chemistry, University of Engineering and Technology, 54890, Lahore, Pakistan aut Altaf Muhammad Institute of Microtechnology, University of Neuchâtel, Neuchatel, Switzerland aut Stoeckli Evans Helen Institute of Microtechnology, University of Neuchâtel, Neuchatel, Switzerland aut Mehmood Rashid Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 685-689 1074-1542 37:10<685 2007 37 10870 https://doi.org/10.1007/s10870-007-9232-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9232-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ahmad Saeed Department of Chemistry, University of Engineering and Technology, 54890, Lahore, Pakistan aut NATIONALLICENCE 700 1- Monim-ul-Mehboob Muhammad Department of Chemistry, University of Engineering and Technology, 54890, Lahore, Pakistan aut NATIONALLICENCE 700 1- Altaf Muhammad Institute of Microtechnology, University of Neuchâtel, Neuchatel, Switzerland aut NATIONALLICENCE 700 1- Stoeckli Evans Helen Institute of Microtechnology, University of Neuchâtel, Neuchatel, Switzerland aut NATIONALLICENCE 700 1- Mehmood Rashid Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 685-689 1074-1542 37:10<685 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer