caa a22 4500 463184688 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10870-007-9223-8 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9223-8 X-ray Crystal Structures of [Et3NH][{(CO)5Mo(P(OCH2CMe2CH2O)O)}2H] and (CO)5Mo{μ-Ph2POPPh2}Mo(CO)5, Two Complexes Derived from the Hydrolysis of Coordinated Chloro-Phosphorous-Donor Ligands [Elektronische Daten] [Samuel Owens Jr., Abha Kaisare, Gary Gray] X-ray crystal structures of [Et3NH][{(CO)5Mo(P(OCH2CMe2CH2O)O)}2H], 3, and (CO)5Mo{μ-Ph2POPPh2}Mo(CO)5, 2, are reported. Crystallization of 3 occurs in P-1 space group with a=9.6944(19) Å, b=10.814(2) Å, c=19.730(4) Å, α=94.24(3)°, β=92.23(3)°, γ=113.47(3)°, Z=4. Crystallization of 2 occurs in C2/c space group with a=10.357(2) Å, b=20.149(4) Å, c=17.155(3) Å, α=90°, β=97.28(3)°, γ=90°, Z=8. Compound 2 is a bimetallic complex with a P-O-P bridging group containing bond distances similar to that of other complexes in which two metal centers are bridged by a single R2POPR2 ligand. Compound 3 contains intermolecular hydrogen bonded P-O-H-O-P linkages with bond distances comparable to those seen in similar structures with intramolecular hydrogen bonding suggesting that the distance is a function of the nature of the bond and not affected by the cis arrangement of the ligands about the metal center. Graphical abstract: X-ray Crystal Structures of [Et 3 NH][{(CO) 5 Mo(P(OCH 2 CMe 2 CH 2 O) O)} 2 H] and (CO) 5 Mo{μ-Ph 2 POPPh 2 }Mo(CO) 5 , Two Complexes Derived from the Hydrolysis of Coordinated Chloro-Phosphorous-Donor Ligands Samuel B. Owens Jr., Abha A. Kaisare and Gary M. Gray X-ray crystal structures of [Et3NH][{(CO)5Mo(P(OCH2CMe2CH2O)O)}2H], 3, and (CO)5Mo{μ-Ph2POPPh2}Mo(CO)5, 2, have been determined. Springer Science+Business Media, LLC, 2007 Molybdenum nationallicence Carbonyl nationallicence Phosphite nationallicence Phosphinite nationallicence Pyrophosphite nationallicence X-Ray structures nationallicence Conformation nationallicence Owens Jr. Samuel Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Kaisare Abha Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Gray Gary Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 655-661 1074-1542 37:10<655 2007 37 10870 https://doi.org/10.1007/s10870-007-9223-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9223-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Owens Jr Samuel Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Kaisare Abha Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Gray Gary Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/10(2007-10-01), 655-661 1074-1542 37:10<655 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer