caa a22 4500 463184696 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20070401xx s 000 0 eng 10.1007/s10870-006-9168-3 doi (NATIONALLICENCE)springer-10.1007/s10870-006-9168-3 Intermolecular interactions involved in the crystal structure of 2-amino-5-methylpyridinium hexabromostannate (IV), (C6H9N2)2[SnBr6] [Elektronische Daten] [Basem Ali, Rawhi Al-Far, Khaldoun Al-Sou'od] The salt bis(2-amino-5-methylpyridinium) hexabromostannate(IV) (C6H9N2)2[SnBr6] is monoclinic, P2 1 /c, with the following cell parameters: a=9.1636(18) Å, b=28.767(7)Å, c=16.956(17)Å, β=101.008(5)°, V=4387.5(17)Å3, Z=8, formula units. X-ray crystallography revealed that the structure can be regarded as a semi-regular three-dimensional array of anions, with pairs of cations forming layers perpendicular to b axis in the cavities between the anions. The cohesion forces that connects molecules in the organic layers are hydrophilic N⋯HCH2 and HN⋯HN hydrogen bonding as well as hydrophobic π-π stacking and CH3⋯π interactions. Cations and anions are connected via strong Br⋯H hydrogen bonding. Springer Science+Business Media, LLC, 2007 Br⋯Br interactions nationallicence Br⋯H hydrogen bonds nationallicence π-π stacking nationallicence X-ray crystal structure nationallicence Ali Basem Department of Chemistry, Al al-Bayt University, Mafraq, Jordan aut Al-Far Rawhi Faculty of Science and IT, Al-Balqa'a Applied University, Salt, Jordan aut Al-Sou'od Khaldoun Department of Chemistry, Al al-Bayt University, Mafraq, Jordan aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/4(2007-04-01), 265-273 1074-1542 37:4<265 2007 37 10870 https://doi.org/10.1007/s10870-006-9168-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9168-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ali Basem Department of Chemistry, Al al-Bayt University, Mafraq, Jordan aut NATIONALLICENCE 700 1- Al-Far Rawhi Faculty of Science and IT, Al-Balqa'a Applied University, Salt, Jordan aut NATIONALLICENCE 700 1- Al-Sou'od Khaldoun Department of Chemistry, Al al-Bayt University, Mafraq, Jordan aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/4(2007-04-01), 265-273 1074-1542 37:4<265 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer