caa a22 4500 463184823 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10870-007-9198-5 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9198-5 Synthesis and Crystal Structures of Bromo(1,10-phenanthroline- N , N ′)tris(2-cyanoethyl)phosphinocopper(I) and Bromo(2,2′-bipyridine- N , N ′)tris(2-cyanoethyl)phosphinocopper(I) [Elektronische Daten] [Sahar Al-Fayez, Laila Abdel-Rahman, Ahsan Shemsi, Zaki Seddigi, Mohammed Fettouhi] The two new complexes bromo(1,10-phenanthroline-N,N′)tris(2-cyanoethyl)phosphinocopper(I) and bromo(2,2′-bipyridine-N,N′)tris(2-cyanoethyl)phosphinocopper(I) were synthesized and their X-ray crystal structures were determined. The first complex crystallizes in the triclinic space group P-1 with the crystal cell parameters a=7.7596(7)Å, b=11.470(1)Å, c=12.803(1)Å, α=78.884(1)°, β=79.759(1)°, γ=86.867(1)°, V=1100.0(2)Å3 and Z=2. The second complex crystallizes in the orthorhombic space group Pbca with the crystal cell parameters a=10.614(1)Å, b=12.345(1)Å, c=31.903(3)Å, V=4180.3(7)Å3 and Z=8. In both compounds, the copper(I) ion is four-coordinate with a distorted tetrahedral geometry. In the 1,10-phenanthroline complex, an intermolecular dipole-dipole interaction between two cyano groups stabilizes an unfavorable synclinal conformation of one cyanoethyl group of the phosphine ligand. Springer Science+Business Media, LLC, 2007 Tris(2-cyanoethyl)phosphine nationallicence Copper(I) complex nationallicence Crystal structure nationallicence Al-Fayez Sahar Chemistry Department, Science Girls College, 31113, Dammam, Saudi Arabia aut Abdel-Rahman Laila Chemistry Department, Science Girls College, 31113, Dammam, Saudi Arabia aut Shemsi Ahsan Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut Seddigi Zaki Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut Fettouhi Mohammed Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 517-521 1074-1542 37:8<517 2007 37 10870 https://doi.org/10.1007/s10870-007-9198-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9198-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Al-Fayez Sahar Chemistry Department, Science Girls College, 31113, Dammam, Saudi Arabia aut NATIONALLICENCE 700 1- Abdel-Rahman Laila Chemistry Department, Science Girls College, 31113, Dammam, Saudi Arabia aut NATIONALLICENCE 700 1- Shemsi Ahsan Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut NATIONALLICENCE 700 1- Seddigi Zaki Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut NATIONALLICENCE 700 1- Fettouhi Mohammed Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 517-521 1074-1542 37:8<517 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer