caa a22 4500 463184858 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10870-007-9208-7 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9208-7 X-Ray Crystal Structure of trans -PdCl2(PPh2C12H7S3)2, a New Morphology [Elektronische Daten] [R. Myrex, Samuel Owens Jr., Gary Gray] Herein we report the crystal structure of trans-PdCl2(PPh2C12H7S3)2, 1, in a different morphology than has previously been reported [Stott et al. (Dalton Trans (4):652-653, 2005]. This structure crystallizes in a P-1 space group with a=9.4249(19)Å, b=11.540(2)Å, c=12.559(3)Å, α=79.07(3)°, β=78.04(3)°, γ=69.44(3)°, Z=1. The earlier structure possessed a P21/n space group. Additionally the terthienyl moieties of 1 demonstrate the anti orientation exclusively while the P21/n space group structure has some syn and even syn/anti mixed geometries included. Springer Science+Business Media, LLC, 2007 Thiophene nationallicence Palladium nationallicence Phosphine nationallicence X-Ray nationallicence Single Crystal Structures nationallicence Conformation nationallicence Myrex R. Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Owens Jr. Samuel Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Gray Gary Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 549-553 1074-1542 37:8<549 2007 37 10870 https://doi.org/10.1007/s10870-007-9208-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9208-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Myrex R. Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Owens Jr Samuel Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Gray Gary Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, 35294-1240, Birmingham, AL, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 549-553 1074-1542 37:8<549 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer