caa a22 4500 463184866 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10870-007-9214-9 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9214-9 Synthesis and Crystal Structure of Copper II and Silver I Complex with 1,4-diazabicyclo[2.2.2]octane[Cu(CBC)2(Dabco)(H2O)] n (1) and [Ag2(HBC)2(Dabco)] n (2) [Elektronische Daten] [Yang Qu, Lijin Su, Jin Wu] Two 1D polymeric complex, [Cu(CBC)2(Dabco)(H2O)] n (1) and [Ag2(HBC)2(Dabco)] n (2) have been synthesized and characterized by X-ray single crystal analysis, where CBCH is p-chlorobenzoic acid, HBCH 2 is 2-hydroxybenzoic acid and Dabco is 1,4-diazabicyclo[2.2.2]octane. Complex 1 has been obtained in high yield by hydrothermal synthesis from CuO and CBCH and Dabco, and complex 2 has been obtain by evaporation of the solvent from silver salicylate and Dabco, 1 crystallizes in the orthorhombic space group Pmn2 1 with a=24.3310(5)Å, b=6.9050(6)Å, c=5.9980(5)Å, Z=2, V=1007.70(4)Å3 and Dx=1.657gcm−3, 2 crystallizes in the monoclinic space group P2 1 /m with a=10.292(3)Å, b=6.913(2)Å, c=14.417(4)Å, β=95.660(5), Z=2, V=1020.8(5)Å3 and Dx=1.959gcm−3. The final R value is 0.0302 for 1323 measured reflections for 1 and the final R value is 0.0684 for 1545 measured reflections for 2. The atomic arrangement is built by infinite one-dimensional polymeric chain in both complexes. These chains are cross-linked by hydrogen bonds involving the coordinated water molecules to form a two-dimensional framework in complex 1. Springer Science+Business Media, LLC, 2007 Crystal structure nationallicence Copper(II) complex nationallicence Silver(I) complex nationallicence Dabco nationallicence Qu Yang Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut Su Lijin Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut Wu Jin Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 579-582 1074-1542 37:8<579 2007 37 10870 https://doi.org/10.1007/s10870-007-9214-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9214-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Qu Yang Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut NATIONALLICENCE 700 1- Su Lijin Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut NATIONALLICENCE 700 1- Wu Jin Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, 430070, Wuhan, P.R. China aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 579-582 1074-1542 37:8<579 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer