caa a22 4500 463184904 CHVBK 20180406164849.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10870-007-9213-x doi (NATIONALLICENCE)springer-10.1007/s10870-007-9213-x Crystal Structure of [Co(NH3)5NO3](NO3)(PF6)·1.5H2O and the Vibrational Bands of its Normal and 15NO3-Enriched Cation [Elektronische Daten] [M. Chacón Villalba, A. Navaza, N. Dupont, J. Marrot, E. Varetti, P. Aymonino] The crystal structure of [Co(NH3)5NO3](NO3)(PF6)·1.5H2O was studied by X-ray diffraction methods in order to obtain the unknown molecular structure of the [Co(NH3)5NO3]2+ cation . The substance crystallizes in the monoclinic system, space group C2/m, with a=18.6231(6) Å, b=7.8757(3) Å, c=9.6434(3) Å and β=95.484(2)°. An infrared and Raman study of the bromide salt was also performed and the spectra interpreted with the aid of 14NO3/15NO3 isotopic replacement and quantum chemistry calculations. Springer Science+Business Media, LLC, 2007 Ammine cobalt complex nationallicence Nitrate nationallicence Structure nationallicence Infrared nationallicence Raman nationallicence Theoretical calculations nationallicence Chacón Villalba M. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut Navaza A. BioMoCeTi UMR 7033 CNRS, UFR SMBH, Université Paris 13, 74 rue Marcel Cachin, 93017, Bobigny Cedex, France aut Dupont N. BioMoCeTi UMR 7033 CNRS, UFR SMBH, Université Paris 13, 74 rue Marcel Cachin, 93017, Bobigny Cedex, France aut Marrot J. Institut Lavoisier de Versailles, UMR 8180 CNRS, 45, avenue des Etats-Unis, 78035, Versailles Cedex, France aut Varetti E. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut Aymonino P. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 573-577 1074-1542 37:8<573 2007 37 10870 https://doi.org/10.1007/s10870-007-9213-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9213-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chacón Villalba M. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut NATIONALLICENCE 700 1- Navaza A. BioMoCeTi UMR 7033 CNRS, UFR SMBH, Université Paris 13, 74 rue Marcel Cachin, 93017, Bobigny Cedex, France aut NATIONALLICENCE 700 1- Dupont N. BioMoCeTi UMR 7033 CNRS, UFR SMBH, Université Paris 13, 74 rue Marcel Cachin, 93017, Bobigny Cedex, France aut NATIONALLICENCE 700 1- Marrot J. Institut Lavoisier de Versailles, UMR 8180 CNRS, 45, avenue des Etats-Unis, 78035, Versailles Cedex, France aut NATIONALLICENCE 700 1- Varetti E. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut NATIONALLICENCE 700 1- Aymonino P. Departamento de Química, Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR), Universidad Nacional de La Plata, C.Correo 962, 1900, La Plata, Argentina aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 37/8(2007-08-01), 573-577 1074-1542 37:8<573 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer