caa a22 4500 463185013 CHVBK 20180406164850.0 cr unu---uuuuu 170326e20070201xx s 000 0 eng 10.1007/s10870-006-9154-9 doi (NATIONALLICENCE)springer-10.1007/s10870-006-9154-9 Synthesis and crystal structure of anhydrous copper suberate: [Cu2(OOC-(CH2)6 -COO)2] [Elektronische Daten] [Assia Djeghri, Fadila Balegroune, Achoura Guehria-Laidoudi, Thierry Roisnel] The title compound [Cu2(OOC-(CH2)6-COO)2] was synthesized and its crystal structure has been determined by single crystal X-ray diffraction methods. The complex crystallizes in the triclinic space group P-1 with a=5.1077(5) Å, b=8.362(2) Å, c=11.378(2) Å, α=93.773(6)°, β=97.587(9)°, γ=90.493('9)° and D cal=1.629mg/m3 for Z=1.  The structure is polymeric and consists of discrete anhydrous centrosymmetric binuclear units [Cu2(OOC-(CH2)6-COO)2]. The two copper(II) centres bridged by the suberate groups in a syn-syn conformation, are in pentacoordinated distorted square-pyramidal coordination environment, with an intramolecular Cu-Cu distance of 2.5793(10) Å. Each binuclear unit, related to the next through μoxo bridges with a Cuμoxo-Cuμoxo separation of 3.2326(10)Å, defines infinite chains of one-edge sharing CuO5 square pyramid. Springer Science+Business Media, LLC, 2006 polymeric structure nationallicence cobalt(II) nationallicence barium(II) nationallicence dicarboxylate nationallicence edge-sharing polyhedra nationallicence structure of [Cu2(OOC-(CH2)6 -COO)2] nationallicence Djeghri Assia Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut Balegroune Fadila Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut Guehria-Laidoudi Achoura Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut Roisnel Thierry Centre de Diffractométrie, Université de Rennes I, Campus de Beaulieu, 35042, Rennes cedex, France aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/2(2007-02-01), 97-101 1074-1542 37:2<97 2007 37 10870 https://doi.org/10.1007/s10870-006-9154-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9154-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Djeghri Assia Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut NATIONALLICENCE 700 1- Balegroune Fadila Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut NATIONALLICENCE 700 1- Guehria-Laidoudi Achoura Laboratoire de Cristallographie-Thermodynamique, Faculté de Chimie, U.S.T.H.B, BP 32 El-Alia, 16111, Bab-Ezzouar, Alger, Algérie aut NATIONALLICENCE 700 1- Roisnel Thierry Centre de Diffractométrie, Université de Rennes I, Campus de Beaulieu, 35042, Rennes cedex, France aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/2(2007-02-01), 97-101 1074-1542 37:2<97 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer