caa a22 4500 463185021 CHVBK 20180406164850.0 cr unu---uuuuu 170326e20070201xx s 000 0 eng 10.1007/s10870-006-9098-0 doi (NATIONALLICENCE)springer-10.1007/s10870-006-9098-0 Synthesis and structure of a novel copper (II) nitrate complex of 2,4-dioxo-4-phenylbutanoic acid [Elektronische Daten] [Brian Landry, Mark Turnbull, Brendan Twamley] 2,4-Dioxo-4-phenylbutanoic acid, 1, was synthesized as a biproduct of the attempted synthesis of 1,6-bisphenyl-1,3,4,6-hexanetetrone. Crystals of [Cu(H2O)(bipy) (L)][Cu(bipy)(L)(NO3)] (H2O)(NO3) (L = 2,4-dioxolato-4-phenylbutanoic acid and bipy = 2,2′-bipyridine), 2, were grown by slow evaporation of a solution of Cu(NO3)2·3 H2O, 2,2′-bipyridine, and 1 in a mixture of ethanol and water. The compound crystallized in the triclinic space group P-1 and is made up of two distinct molecular units each with approximately square pyramidal geometry: a = 10.663(2)Å, b = 13.275(3)Å, c = 15.071(3)Å, α = 80.26(3)°, β = 74.13(3)°, γ = 89.12(3)°. The copper ions are chelated by molecules of 1 and molecules of bipyridine. The molecular units are arrayed in rows held together by pi-stacking interactions and hydrogen bonding. Springer Science+Business Media, Inc., 2006 Copper(II) nationallicence Acac analog nationallicence Dioxophenylbutanoic acid nationallicence Landry Brian Carlson School of Chemistry and Biochemistry, Clark University, 950 Main Street, 01610, Worcester, MA aut Turnbull Mark Carlson School of Chemistry and Biochemistry, Clark University, 950 Main Street, 01610, Worcester, MA aut Twamley Brendan University Research Office, University of Idaho, ID, Moscow, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/2(2007-02-01), 81-86 1074-1542 37:2<81 2007 37 10870 https://doi.org/10.1007/s10870-006-9098-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-006-9098-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Landry Brian Carlson School of Chemistry and Biochemistry, Clark University, 950 Main Street, 01610, Worcester, MA aut NATIONALLICENCE 700 1- Turnbull Mark Carlson School of Chemistry and Biochemistry, Clark University, 950 Main Street, 01610, Worcester, MA aut NATIONALLICENCE 700 1- Twamley Brendan University Research Office, University of Idaho, ID, Moscow, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/2(2007-02-01), 81-86 1074-1542 37:2<81 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer