caa a22 4500 46318517X CHVBK 20180406164850.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10870-007-9244-3 doi (NATIONALLICENCE)springer-10.1007/s10870-007-9244-3 Tri-metal Secondary Building Units: Toward the Design of Thermally Robust Crystalline Coordination Polymers [Elektronische Daten] [Brian Luisi, Zhenbo Ma, Brian Moulton] Three new crystalline coordination polymers [Mn3(TDC)4(H2O)4](2,6-lutidine)2(H2O)3 1, P-1, a=11.351(3), b=11.391(3), c=11.480(3), α=112.838(4), β=90.696(4), γ=99.328(4); [Zn3(1,4-BDC)3(EtOH)2] 2, C2/c, a=19.1308(9), b=10.6088(5), c=16.2221(7), β=108.79(1); and [Zn3(1,3-BDC)3(py)2](MeOH) 3, P2(1)/c, a=17.142(3), b=21.544(4), c=11.805(2), β=106.441(3); TDC=2,5-thiophenedicarboxylate, BDC=benzedicarboxylate, have been synthesized by linking tri-metal nodes with poly-carboxylate ligands. Single crystal x-ray analysis shows that 1 is composed of (4,4) 2-D grids with A-A stacking while 2 is comprised of (6,3) triangular networks in an A-B-C stacking pattern and 3 has formed a distorted cubic diamondoid topology. Tri-metal nodes are located at the vertexes of each network. Thermal gravimetric analysis demonstrates that 1 and 2 are thermally robust structures with network decomposition temperatures of 375°C and 460°C respectively. Graphical abstract: Tri-metal Secondary Building Units: Toward the Design of Thermally Robust Crystalline Coordination Polymers Brian S. Luisi, Zhenbo Ma and Brian Moulton* Tri-metal nodes are shown to be an advantageous target in the synthesis of 2-D crystalline coordination polymers with high thermal stability. Springer Science+Business Media, LLC, 2007 Supramolecular nationallicence Coordination polymer nationallicence Thermal properties nationallicence Crystallography nationallicence Luisi Brian Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut Ma Zhenbo Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut Moulton Brian Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/11(2007-11-01), 743-747 1074-1542 37:11<743 2007 37 10870 https://doi.org/10.1007/s10870-007-9244-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10870-007-9244-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Luisi Brian Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut NATIONALLICENCE 700 1- Ma Zhenbo Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut NATIONALLICENCE 700 1- Moulton Brian Department of Chemistry, Brown University, 324 Brook Street, 02912, Providence, RI, USA aut NATIONALLICENCE 773 0- Journal of Chemical Crystallography Springer US; http://www.springer-ny.com 37/11(2007-11-01), 743-747 1074-1542 37:11<743 2007 37 10870 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer