caa a22 4500 463188020 CHVBK 20180406164859.0 cr unu---uuuuu 170326e20070401xx s 000 0 eng 10.1007/s10973-006-8081-5 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8081-5 Thermalbehaviour of some Al(III)-Mg(II) polynuclear coordination compounds with polycarboxylicacid anions as ligands, precursors of aluminates [Elektronische Daten] [O. Carp, L. Patron, I. Mindru, C. Suciu] A TG, DTG and DTA study of three polynuclear coordination compounds, containing Al(III)-Mg(II), namely (NH4)4[Al2Mg(C4O5H4)4(OH)4]⋅2H2O, (NH4)4[MgAl2(C4H4O6)4(OH)4]⋅3H2O and (NH4)2[Al2Mg(C6O7H11)5(OH)5]⋅3H2O, has been reported together with the associated thermal decomposition mechanism rationalized in terms of intermediate products. As decomposition end-product, magnesium-aluminum spinel is obtained. The values of MgAl2O4 mean crystallite size depend on the anionic ligand contained by the precursor compound, varying in the order: malate (143 Å) ligand contained by the precursor compound, varying in the order: malate (143 Å) Springer-Verlag, 2007 magnesium-aluminum complexes nationallicence magnesium-aluminum spinel nationallicence thermal analysis nationallicence Carp O. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut Patron L. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut Mindru I. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut Suciu C. National Institute of Environmental Protection, Splaiul Independentei No. 254, sector 6, Bucharest, Romania aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/1(2007-04-01), 77-81 1388-6150 88:1<77 2007 88 10973 https://doi.org/10.1007/s10973-006-8081-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8081-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Carp O. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut NATIONALLICENCE 700 1- Patron L. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut NATIONALLICENCE 700 1- Mindru I. Institute of Physical Chemistry, Splaiul Independentei No. 202, 060021, Bucharest, Romania aut NATIONALLICENCE 700 1- Suciu C. National Institute of Environmental Protection, Splaiul Independentei No. 254, sector 6, Bucharest, Romania aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/1(2007-04-01), 77-81 1388-6150 88:1<77 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer